102535-89-7Relevant articles and documents
Rhodium(II)-catalyzed aziridinations and ch insertions with [N-(p-nitrobenzenesulfonyl)imino]phenyliodinane
Mueller, Paul,Baud, Corine,Jacquier, Yvan,Moran, Mary,Naegeli, Ivo
, p. 341 - 347 (1996)
The [Rh2(OAc)4]-catalyzed decomposition of NsN=IPh {[N-(p-nitrobenzenesulfonyl)imino]phenyliodinane} in the presence of olefins affords aziridines in yields of up to 85%. The aziridination of cis-hex-2-ene and cis-β-methylstyrene is stereospecific, but, cis-stilbene affords a 3:1 mixture of cis- and trans-aziridines in low yield. With chiral Rh(II) catalysts, optically active aziridines are formed having enantiomeric excesses of up to 73%. The NsN-IPh-[Rh2(OAc)4] system is also efficient for the allylic amination of olefins and for insertion into CH bonds, activated by phenyl or oxygen substituents.
Generation and Ring Opening of Aziridines in Telescoped Continuous Flow Processes
Hsueh, Nathanael,Clarkson, Guy J.,Shipman, Michael
supporting information, p. 3632 - 3635 (2015/07/28)
A simple method for the preparation of a variety of N-sulfonyl aziridines (10 examples) from 1,2-amino alcohols under continuous flow conditions is described. Using flow based methods, the aziridines can be further ring opened with oxygen, carbon, and hal
Catalyst-free aziridination and unexpected homologation of aziridines from imines
Branco, Paula Serio,Raje, Vivek Prabhakar,Dourado, Jorge,Gordo, Joana
experimental part, p. 2968 - 2974 (2010/09/06)
Aziridination and unpredicted homologation reaction of N-sulfonylimines were achieved easily with a very simple, rapid and mild procedure through the use of diazomethane without the presence of any catalyst. The method represents an attractive alternative
