1027543-09-4

Basic information

• Product Name: 3-Butenyl 2,4-dinitrophenyl ether
• Synonyms: 3-Butenyl 2,4-dinitrophenyl ether
• CAS NO: 1027543-09-4
• Molecular Weight: 238.2
• Mol File: 1027543-09-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Butenyl 2,4-dinitrophenyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Butenyl 2,4-dinitrophenyl ether(1027543-09-4)
• EPA Substance Registry System: 3-Butenyl 2,4-dinitrophenyl ether(1027543-09-4)

Safety Data

• Hazardous Substances Data: 1027543-09-4(Hazardous Substances Data)

Upstream product

• 627-27-0 homoalylic alcohol 
• 70-34-8 2,4-Dinitrofluorobenzene 

Downstream Products

• 51-28-5 2,4-Dinitrophenol 

Relevant articles and documents

Hydrolysis of ethers of 2,4-dinitrophenol. No evidence for a single electron transfer mechanism

The reactions of 3-butenyl 2,4-dinitrophenyl ether (1), allyl 2,4- dinitrophenyl ether (5), and n-butyl 2,4-dinitrophenyl ether (6) with KOH in two DMSO-water mixtures (50% v/v and 70% v/v) were studied. In all cases, no evidence was found for a single electron transfer mechanism; 2,4- dinitrophenol was the only product formed. The reaction follows the classical S(N)Ar mechanism. The order of reactivity is 5 > 1 > 6 in both solvents, although the reactivities differ only by factors of 1.4 and 2 in 50 and 70% DMSO, respectively.