1028729-05-6

Basic information

• Product Name: 4-(Naphthalene-1-yl)phenylboronic acid pinacol ester
• Synonyms: 4-(Naphthalene-1-yl)phenylboronic acid pinacol ester;4,4,5,5-Tetramethyl-2-(4-(naphthalen-1-yl)phenyl)-1,3,2-dioxaborolane
• CAS NO: 1028729-05-6
• Molecular Formula: C₂₂H₂₃BO₂
• Molecular Weight: 330.23
• Mol File: 1028729-05-6.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 457.4±24.0 °C(Predicted)
• Appearance: /
• Density: 1.10±0.1 g/cm3(Predicted)
• CAS DataBase Reference: 4-(Naphthalene-1-yl)phenylboronic acid pinacol ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(Naphthalene-1-yl)phenylboronic acid pinacol ester(1028729-05-6)
• EPA Substance Registry System: 4-(Naphthalene-1-yl)phenylboronic acid pinacol ester(1028729-05-6)

Safety Data

• Hazardous Substances Data: 1028729-05-6(Hazardous Substances Data)

Usage

General Description

4-(Naphthalene-1-yl)phenylboronic acid pinacol ester is a chemical compound that is derived from phenylboronic acid and pinacol. It is commonly used as a reagent in organic synthesis for the synthesis of various aromatic compounds. 4-(Naphthalene-1-yl)phenylboronic acid pinacol ester has important applications in the field of pharmaceuticals, agrochemicals, and materials science. It is often utilized in the formation of carbon-carbon and carbon-heteroatom bonds, making it a valuable tool for the development of new chemical entities. Its unique structure and reactivity make it an important building block for the creation of complex molecules, and it is often used in research and development for drug discovery and materials design.

Upstream product

• 92964-54-0 1-(4-hydroxyphenyl)naphthalene 
• 106-39-8 bromochlorobenzene 
• 13922-41-3 1-Naphthylboronic acid 
• 24382-97-6 1-(4-chlorophenyl)naphthalene 
• 73183-34-3 bis(pinacol)diborane 
• 61676-62-8 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 204530-94-9 1-(4-bromo-phenyl)-naphthalene 
• 106-37-6 1.4-dibromobenzene 
• 572-52-1 1-(4-fluorophenyl)naphthalene 

Relevant articles and documents

Development and Mechanistic Studies of Iron-Catalyzed Construction of Csp2-B Bonds via C-O Bond Activation

Herein we describe an iron-catalyzed borylation of alkenyl and aryl carbamates through the activation of a C-O bond. This protocol exhibits high efficiency, a broad substrate scope, and the late-stage borylation of biorelevant compounds, thus providing potential applications in medicinal chemistry. Moreover, this method enables orthogonal transformations of phenol derivatives and also offers good opportunities for the synthesis of multisubstituted arenes. Preliminary mechanistic studies suggest that a FeII/FeIII catalytic cycle via a radical pathway might be involved in the reaction.

LiHMDS-Promoted Palladium or Iron-Catalyzed ipso-Defluoroborylation of Aryl Fluorides

A novel and efficient method for the synthesis of arylboronic acid pinacol esters via a palladium- or iron-catalyzed cross-coupling reaction of aryl fluorides with bis(pinacolato)diboron (B2pin2) in the presence of LiHMDS was developed. The Pd-catalyzed defluoroborylation of fluoroarenes is compatible with a variety of functional groups such as primary and secondary amine, ketone, trifluoromethyl, alkoxy, and boryl. Remarkably, no external ligand is required for enhanced conversion efficiency.

COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND AN ELECTRONIC DEVICE THEREOF

The present invention relates to: a compound which can obtain high light emitting efficiency and low driving voltage of a device and expand lifespan of the device; an organic electric device using the same; and an electronic apparatus thereof. The present invention provides a compound represented by chemical formula 1, and provides an organic electric device using the compound represented by the chemical formula and an electronic apparatus thereof.(110) Substrate(120) Positive electrode(130) Hole injection layer(140) Hole transport layer(141) Buffer layer(150) Light emitting layer(151) Light-emitting assisting layer(160) Electron transport layer(170) Electron injection layer(180) Negative electrodeCOPYRIGHT KIPO 2016