10360-75-5Relevant articles and documents
Synthesis of diethoxy(phenyl)silane and its polycondensation in acetic acid
Milenin,Kalinina,Demchenko,Vasilenko,Muzafarov
, (2013)
Low-temperature reaction between phenylmagnesium chloride and triethoxysilane at lowered affords diethoxy(phenyl)silane, whose polycondensation in acetic acid gives oligomeric (phenyl)hydrosiloxanes.
Synthesis of tri- and tetracyclosiloxanes with functional groups attached to the silicon atoms
Zhdanov,Andrianov,Malykhin,Emel'yanov
, p. 2241 - 2244 (2007/10/16)
1. The hydrolytic condensation of phenylvinyldichlorosilane fails to yield phenylvinylcyclosiloxanes, and instead 1,3-dihydroxy-1,3-diphenyldivinyldisiloxane is formed. 2. A study was made of the heterofunctional condensation of 1,3-dihydroxy-1,3-diphenyldivinyldisiloxane with phenylvinyldichlorosilane and 1,3-dichloro-1,3-diphenyldivinyldisiloxane, and it was shown that trivinyltriphenylcyclotrisiloxane and tetravinyltetraphenylcyclotetrasiloxane can be synthesized by the given method. 3. The side process of benzene cleavage occurs during the hydrolytic condensation of phenyldichlorosilane. Tetraphenylcyclotetrasiloxane can be obtained by the hydrolytic condensation of 1,3-dichloro-1,3diphenyldisiloxane.