1039027-73-0

Basic information

• Product Name: 5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)porphyrinato-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾zinc(II)
• Synonyms: 5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)porphyrinato-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾zinc(II)
• CAS NO: 1039027-73-0
• Molecular Weight: 1002.28
• Mol File: 1039027-73-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)porphyrinato-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾zinc(II)(CAS DataBase Reference)
• NIST Chemistry Reference: 5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)porphyrinato-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾zinc(II)(1039027-73-0)
• EPA Substance Registry System: 5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)porphyrinato-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾zinc(II)(1039027-73-0)

Safety Data

• Hazardous Substances Data: 1039027-73-0(Hazardous Substances Data)

Upstream product

• 215313-78-3 [10,20-bis-(3,5-di-tert-butylphenyl)-5,15-bis-bromoporphyrinato]zinc(II) 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 
• 187387-14-0 [5,15-bis-(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) 
• 215313-78-3 [5,15-dibromo-10,20-bis-(3,5-di-tert-butyphenyl)porphyrinato]zinc(II) 

Downstream Products

• 1202170-65-7 5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4-bromophenyl)porphyrinato-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾zinc(II) 
• 1225201-91-1 [5-[10-(1,8-dioctyloxyanthracene)]-10,20-bis-(3,5-di-tert-butylphenyl)porphyrinato] zinc(II) 
• 1225201-87-5 [5,15-di-[10-(1,8-dioctyloxyanthracene)]-10,20-bis-(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) 
• 1225201-92-2 [5-[10-(1,8-bis(2,4,6-trimethylphenoxy)anthracene)]-10,20-bis-(3,5-di-tert-butylphenyl)-porphyrinato]zinc(II) 
• 1225201-88-6 [5,15-[10-(1,8-bis(2,4,6-trimethylphenoxy)anthracene)]-10,20-bis-(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) 
• 1202642-10-1 C₉₆H₉₇BN₈O₂Zn₂ 
• 1039027-47-8 di-n-hexyl 3,3'-[10,20-bis(3,5-di-tertbutylphenyl)porphyrinate(zinc)-5,15-diyl]dipropanoate 

Relevant articles and documents

Synthesis and investigation of donor-porphyrin-acceptor triads with long-lived photo-induced charge-separate states

Two donor-porphyrin-acceptor triads have been synthesized using a versatile Suzuki-coupling route. This synthetic strategy allows the powerful donor tetraalkylphenylenediamine (TAPD) to be introduced into tetraarylporphyrin-based triads without protection. The thermodynamics and kinetics of electron transfer in the new triads are compared with a previously reported octaalkyldiphenyl-porphyrin triad exhibiting a long-lived spin-polarized charge separate state (CSS), from theoretical and experimental perspectives, in both fluid solution and in a frozen solvent glass. We show that the less favorable oxidation potential of the tetraaryl-porphyrin core can be offset by using C60, as a better electron-acceptor than triptycenenaphthoquinone (TNQ). The C60-porphyrin-TAPD triad gives a spin-polarized charge-separated state that can be observed by EPR-spectroscopy, with a mean lifetime of 16 ms at 10 K, which is longer than in the previously reported TNQ-porphyrin-TAPD triad, following the predicted trend from calculated charge-recombination rates.

FUSING PORPHYRINS WITH POLYCYCLIC AROMATIC HYDROCARBONS AND HETEROCYCLES FOR OPTOELECTRIC APPLICATIONS

A compound that can be used as a donor material in organic photovoltaic devices comprising a non-activated porphyrin fused with one or more non-activated polycyclic aromatic rings or one or more non-activated heterocyclic rings can be obtained by a thermal fusion process. By heating the reaction mixture of non-activated porphyrins with non-activated polycyclic aromatic rings or heterocyclic rings to a fusion temperature and holding for a predetermined time, fusion of one or more polycyciic rings or heterocyclic rings to the non-activated porphyrin core in meso,β fashion is achieved resulting in hybrid structures containing a distorted porphyrin ring with annulated aromatic rings. The porphyrin core can be olygoporphyrins.

Post-modification of meso-meso-linked porphyrin arrays by iridium and rhodium catalyses for tuning of energy gap

meso-meso-Linked diporphyrins fabricated with multiple unsaturated carboxylic acid groups are efficiently synthesized by the use of transition-metal catalysis. Iridium-catalyzed direct borylation of meso-meso-linked diporphyrins furnish multi-borylated di