103985-40-6

Basic information

• Product Name: 1-Cyclohexene-1-methanol, 2,4,4-trimethyl-
• CAS NO: 103985-40-6
• Molecular Formula: C10H18O
• Molecular Weight: 154.252
• Mol File: 103985-40-6.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1-Cyclohexene-1-methanol, 2,4,4-trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Cyclohexene-1-methanol, 2,4,4-trimethyl-(103985-40-6)
• EPA Substance Registry System: 1-Cyclohexene-1-methanol, 2,4,4-trimethyl-(103985-40-6)

Safety Data

• Hazardous Substances Data: 103985-40-6(Hazardous Substances Data)

Upstream product

• 638-10-8 ethyl 3-methylbut-2-enoate 
• 870-63-3 prenyl bromide 
• 2230-70-8 2,4,4-trimethyl-cyclohexanone 
• 814-78-8 3-Methyl-3-buten-2-one 
• 5939-87-7 (2,4,4-trimethyl-1-cyclohexene)carbaldehyde 
• 13395-71-6 2,4,4-trimethyl-2-cyclohexenone 
• 1629-58-9 4-penten-3-one 
• 855657-56-6 isopropenyl-(3-methyl-but-2-enyl)-malonic acid diethyl ester 
• 70092-25-0 1-(2,4,4-trimethyl-cyclohex-1-enyl)-ethanone 
• 503-46-8 1,5,5-trimethylcyclohexene 
• 185248-59-3 2-(Diethoxy-phosphoryloxy)-4,4-dimethyl-cyclohex-1-enecarboxylic acid methyl ester 
• 32767-46-7 methyl 4,4-dimethyl-2-oxocyclohexancarboxylate 
• 2979-19-3 3,3-dimethylcyclohexanone 
• 1845-54-1 (±)-ethyl 5-methyl-2-(prop-1-en-2-yl)hex-4-enoate 

Downstream Products

• 67451-72-3 1-(bromomethyl)-2,4,4-trimethyl-1-cyclohexene 
• 5939-87-7 (2,4,4-trimethyl-1-cyclohexene)carbaldehyde 
• 937811-11-5 1-[3,4-dimethoxy-2-methyl-6-(2,4,4-trimethyl-1-cyclohexen-1-ylacetyl)-9H-carbazol-1-yl]propan-2-yl acetate 
• 207505-90-6 1-[3,4-dimethoxy-2-methyl-6-(2,4,4-trimethyl-1-cyclohexen-1-ylmethyl)-9H-carbazol-1-yl]propan-2-yl acetate 
• 122228-60-8 lavanducyanin 3 
• 117147-14-5 isopropenyl-(2,4,4-trimethyl-cyclohex-1-enylmethyl)-malonic acid diethyl ester 
• 101262-11-7 3-methyl-2-(2,4,4-trimethyl-cyclohex-1-enylmethyl)-but-3-enoic acid 
• 207505-91-7 1-[3,4-dimethoxy-2-methyl-6-(2,4,4-trimethyl-1-cyclohexen-1-ylmethyl)(9H-carbazol-1-yl)]propan-2-ol 

Relevant articles and documents

Total Syntheses of Pyocyanin, Lavanducyanin, and Marinocyanins A and B

Total syntheses of pyocyanin, lavanducyanin, and marinocyanins A and B have been accomplished. The N-substituted phenazin-1-one skeleton, a common framework of these natural products, was constructed through the oxidative condensation of pyrogallol with N-substituted benzene-1,2-diamine under an oxygen atmosphere in a single step. Regioselective bromination with N-bromosuccinimide at the C-2 position of N-alkylated phenazin-1-ones afforded brominated natural products.

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Method for producing [beta]-cyclolavandulal and derivative of same

A given compound is synthesized simply, efficiently, and selectively. Specifically, provided are a method for producing (2,4,4-trimethyl-1-cyclohexene)carbaldehyde including at least a step for obtaining a 2,4,4-trimethyl-2-cyclohexenylidene methyl ether compound (2) by reacting the carbonyl groups of 2,4,4-trimethyl-2-cyclohexenone (1) and a step for obtaining (2,4,4-trimethyl-1-cyclohexene)carbaldehyde (3) by hydrolyzing (2), a method for producing (2,4,4-trimethyl-1-cyclohexene)methanol including at least a step for obtaining (2,4,4-trimethyl-1-cyclohexene)methanol (4) by reducing (3), and a method for producing a (2,4,4-trimethyl-1-cyclohexenyl)methyl ester compound including at least a step for obtaining a (2,4,4-trimethyl-1-cyclohexenyl)methyl ester compound (5) by esterifying (4).

Transition metals in organic synthesis, Part 98.1 Transition metal mediated total synthesis of the potent neuronal cell protecting alkaloid (±)-lavanduquinocin

An efficient total synthesis of (±)-lavanduquinocin, a potent neuronal cell protecting alkaloid from Streptomyces viridochromogenes, is reported. Key-steps are an iron-mediated one-pot construction of the carbazole framework and a nickel-mediated coupling reaction. ARKAT-USA, Inc.