1040749-50-5

Basic information

• Product Name: C₁₈H₁₀N₂(C₆H₄OC₆H₁₂OC₅H₉O)2
• Synonyms: C₁₈H₁₀N₂(C₆H₄OC₆H₁₂OC₅H₉O)2
• CAS NO: 1040749-50-5
• Molecular Weight: 809.058
• Mol File: 1040749-50-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₈H₁₀N₂(C₆H₄OC₆H₁₂OC₅H₉O)2(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₈H₁₀N₂(C₆H₄OC₆H₁₂OC₅H₉O)2(1040749-50-5)
• EPA Substance Registry System: C₁₈H₁₀N₂(C₆H₄OC₆H₁₂OC₅H₉O)2(1040749-50-5)

Safety Data

• Hazardous Substances Data: 1040749-50-5(Hazardous Substances Data)

Upstream product

• 880644-67-7 8,8'-bis(4-methoxyphenyl)-3,3'-biisoquinoline 
• 880644-68-8 4,4'-(3,3'-biisoquinoline-8,8'-diyl)diphenol 
• 53963-10-3 2-[(6-bromohexyl)oxy]tetrahydro-2H-pyran 

Downstream Products

• 1040749-46-9 C₁₂H₆N₂(C₆H₄OC₃H₆)2C₁₅H₉N₃Cu(C₁₀H₆N₂(C₆H₄OCH₃)2)⁽¹⁺⁾*PF₆^(1-)=C₁₂H₆N₂(C₆H₄OC₃H₆)2C₁₅H₉N₃Cu(C₁₀H₆N₂(C₆H₄OCH₃)2)PF₆ 
• 145145-17-1 Cu(6,6'-bis(2-hydroxyphenyl)-2,2'-bipyridine-2H) 

Relevant articles and documents

Pirouetting copper(I)-assembled pseudo-rotaxanes: Strong influence of the axle structure on the motion rate

Based on the gathering and threading effect of copper(I), three different pseudo-rotaxanes have been prepared and characterised in solution. They consist of the same two-chelate ring and various coordinating fragments threaded through the ring. The ring-incorporated chelates are a 2,2′,6′,6″- terpyridine (terpy) unit and a 2,9-diphenyl-1,10-phenanthroline (dpp) motif. The threaded chelates are a 2,9-bis(p-anisyl)-1,10-phenanthroline (dap), a 6,6′-bis(p-anisyl)-2,2′-bipyridine (dabipy) or a 8,8′-diphenyl-3,3′-biisoquinoline (dpbiiq) derivative. Using electrochemical techniques, the pirouetting motions of the axle within the ring through which it is threaded have been investigated. In dichloromethane/ acetonitrile, a strong dependence of the motion rate on the structure of the threaded chelate has been observed, evidencing that rigidity of the thread-contained chelate and steric hindrance lead to slow moving molecular machines. Pirouetting is the main dynamic process observed but unthreading of the string-like organic component represents another minor electrochemically induced reaction. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.