104173-36-6Relevant articles and documents
Deamination Reactions, 45. Decomposition of 1-Arylcyclopropanediazonium Ions
Kirmse, Wolfgang,Rode, Jutta
, p. 3694 - 3703 (2007/10/02)
1-Arylcyclopropanediazonium ions have been generated by alkaline cleavage of the analogous nitrosocarbamates in methanol.With increasing ?-donor capacity of the aryl groups, retention of the three-membered ring was enhanced while the stereoselectivity (as probed with the aid of 2-D labels) was diminished or entirely lost (4-methoxyphenyl).Where applicable, the stereoselectivity of ring opening is inferior to that of nucleophilic displacement.The data may be interpreted in terms of competing reactions (ks, kc, kΔ) of the cyclopropanediazonium ions.