1041766-84-0Relevant articles and documents
Direct oxidative cyanation based on the concept of site isolation
Tajima, Toshiki,Nakajima, Atsushi
, p. 10496 - 10497 (2008)
On the basis of the concept of site isolation, we have successfully demonstrated direct oxidative cyanation of various organic compounds, which even have higher oxidation potentials compared to that of cyanide, by using a polystyrene-supported quaternary ammonium cyanide. Copyright
Method for preparing alpha-aminonitrile and product and application thereof
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Paragraph 0061-0066, (2021/02/24)
The invention discloses a method for preparing alpha-aminonitrile, which comprises the following steps: by using tertiary amine and benzoyl cyanide as reactants, carrying out visible light irradiationin an organic solvent under the condition of oxygen or
PIFA-Promoted, Solvent-Controlled Selective Functionalization of C(sp2)-H or C(sp3)-H: Nitration via C-N Bond Cleavage of CH3NO2, Cyanation, or Oxygenation in Water
Mudithanapelli, Chandrashekar,Dhorma, Lama Prema,Kim, Mi-Hyun
, (2019/05/07)
A novel nitration (via C(sp3)-N breaking/C(sp2)-N formation with CH3NO2) mediated by [bis(trifluoroacetoxy)iodo]benzene (PIFA) is described. The NO2 transfer from CH3NO2 to the aromatic group of the substrate is possible with careful selection of the solvent, NaX, and oxidant. In addition, the solvent-controlled C(sp2)-H functionalization can shift to an α-C(sp3)-H functionalization (cyanation or oxygenation) of the α-C(sp3)-H of cyclic amines.
