104197-48-0

Basic information

• Product Name: 1-bromo-1-(p-(trifluoromethyl)phenyl)-2-n-butylcyclopropane
• CAS NO: 104197-48-0
• Molecular Weight: 321.18
• Mol File: 104197-48-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-bromo-1-(p-(trifluoromethyl)phenyl)-2-n-butylcyclopropane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-bromo-1-(p-(trifluoromethyl)phenyl)-2-n-butylcyclopropane(104197-48-0)
• EPA Substance Registry System: 1-bromo-1-(p-(trifluoromethyl)phenyl)-2-n-butylcyclopropane(104197-48-0)

Safety Data

• Hazardous Substances Data: 104197-48-0(Hazardous Substances Data)

Upstream product

• 592-41-6 1-hexene 
• 95911-64-1 3-(p-(trifluoromethyl)phenyl)diazirine 

Relevant articles and documents

Activation Parameters for the Additions of Arylhalocarbenes to Alkenes

By use of nanosecond laser flash photolytic methods, absolute rate constants have been obtained for the additions of p-(trifluoromethyl)phenylbromocarbene (CF3C6H4CBr), phenylbromocarbene (PhCBr), phenylchlorocarbene (PhCCl), phenylfluorocarbene (PhCF), and p-methoxyphenylfluorocarbene (CH3OC6H4CF) to tetramethylethylene (TME) and 1-hexene.The rate constants ranged from 1.7 x 109 (CF3C6H4CBr/TME) to 5.0 x 104 L/(M.s) (CH3OC6H4CF)/1-hexene); classical structure/reactivity relations were obeyed.Determination of the rate constants at temperatures between 315 and 200 K gave Ea, logA, ΔH*, ΔS*, and ΔG* for the 10 reactions.All of thereactions were dominated by ΔS*, ΔG* ranged from 5.0 to 11 kcal/mol for the fastest and slowest reactions.Negative values of Ea were observed some of the faster reactions at higher temperatures.These results are analyzed in terms of single-step addition reactions where ΔG* is dominated by ΔS* and, alternatively, in terms of a two-steps machanism proceeding through a carbene-alkene complex.