104306-37-8

Basic information

• Product Name: 1-tert-butyldimethylsiloxyhexyl phenyl sulfide
• CAS NO: 104306-37-8
• Molecular Weight: 324.603
• Mol File: 104306-37-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-tert-butyldimethylsiloxyhexyl phenyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: 1-tert-butyldimethylsiloxyhexyl phenyl sulfide(104306-37-8)
• EPA Substance Registry System: 1-tert-butyldimethylsiloxyhexyl phenyl sulfide(104306-37-8)

Safety Data

• Hazardous Substances Data: 104306-37-8(Hazardous Substances Data)

Upstream product

• 117939-92-1 n-hexyl phenyl sulfoxide 
• 77086-38-5 ketene t-butyldimethylsilyl methyl acetal 

Relevant articles and documents

Chemistry of O-Silylated Ketene Acetals: Preparation of α-Siloxy Phenyl Sulfides and Methyl 3-(Phenylthio)butyrates from Alkyl Phenyl Sulfoxides

Treatment of alkyl phenyl sulfoxides (2a-h) with O-methyl-O-tert-butyldimethylsilyl ketene acetal (1a) in dry acetonitrile in the presence of a catalytic amount of zinc iodide caused a Pummerer-type rearrangement to give α-siloxy phenyl sulfides (3a-h) under mild conditions.On the oder hand, treatment of the sulfoxide (2d) with O-methyl-O-trimethylsilyl ketene acetals (1b,c) under similar conditions gave carbon-carbon bond-formed products, methyl 3-(phenylthio)-butyrates (8 and 9).Keywords - O-methyl-O-tert-butyldimethylsilyl ketene acetal; alkyl phenyl sulfoxide; Pummerer rearrangement; α-siloxy phenyl sulfide; O-methyl-O-trimethylsilyl ketene acetal; carbon-carbon bond forming reaction; methyl 3-(phenylthio)butyrate; α-siloxy sulfide reaction