104499-35-6

Basic information

• Product Name: (4R,5S)-3-(N-benzyloxycarbonyl-DL-valinyl)-4-methyl-5-phenyl-1,3-oxazolidine-2-thione
• CAS NO: 104499-35-6
• Molecular Weight: 426.536
• Mol File: 104499-35-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4R,5S)-3-(N-benzyloxycarbonyl-DL-valinyl)-4-methyl-5-phenyl-1,3-oxazolidine-2-thione(CAS DataBase Reference)
• NIST Chemistry Reference: (4R,5S)-3-(N-benzyloxycarbonyl-DL-valinyl)-4-methyl-5-phenyl-1,3-oxazolidine-2-thione(104499-35-6)
• EPA Substance Registry System: (4R,5S)-3-(N-benzyloxycarbonyl-DL-valinyl)-4-methyl-5-phenyl-1,3-oxazolidine-2-thione(104499-35-6)

Safety Data

• Hazardous Substances Data: 104499-35-6(Hazardous Substances Data)

Upstream product

• 104499-16-3 (4R,5S)-3-benzoyl-4-methyl-5-phenyl-1,3-oxazolidine-2-thione 
• 98290-53-0 (4R,5S)-3-propanoyl-4-methyl-5-phenyl-1,3-oxazolidine-2-thione 
• 1149-26-4 N-benzyloxycarbonylvaline 
• 91794-28-4 (4R,5S)-(+)-4-methyl-5-phenyl-1,3-oxazolidine-2-thione 

Relevant articles and documents

Investigation of New Chiral 1,3-Oxazolidine-2-thiones: Analytical Separation and Optical Resolution of Racemic Carboxylic Acids and Amino Acids

New chiral five-memebered heterocycles, (4S)-(4) and (4R)-4-ethyl-1,3-oxazolidine-2-thione (5), (4S)-4-isopropyl-1,3-oxazolidine-2-thione (6), and (4R,5S)-4-methyl-5-phenyl-1,3-oxazolidine-2-thione (7) have been developed.Among these heterocycles, (4R,5S)-MPOT (7) proved to be an excellent chiral reagent for analytical and efficient separation of racemic products from transformations of chiral carboxylic acids and amino acids.