104888-85-9

Basic information

• Product Name: PtCl(ClC₆H₃CHN₂CH(ClC₆H₄))(P(C₂H₅)3)2
• CAS NO: 104888-85-9
• Molecular Weight: 742.996
• Mol File: 104888-85-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: PtCl(ClC₆H₃CHN₂CH(ClC₆H₄))(P(C₂H₅)3)2(CAS DataBase Reference)
• NIST Chemistry Reference: PtCl(ClC₆H₃CHN₂CH(ClC₆H₄))(P(C₂H₅)3)2(104888-85-9)
• EPA Substance Registry System: PtCl(ClC₆H₃CHN₂CH(ClC₆H₄))(P(C₂H₅)3)2(104888-85-9)

Safety Data

• Hazardous Substances Data: 104888-85-9(Hazardous Substances Data)

Upstream product

• 554-70-1 triethylphosphine 

Relevant articles and documents

MONO- AND DI-CYCLOPLATINATED DERIVATIVES OF BENZALAZINES

The reaction of (p-RC6H4CH=N)2 (R = NO2, Cl, H, NMe2) with PtCl42- has been studied.Cyclometallation only occurs when R = Cl, giving mixtures of the mono- and di-metallated compounds, and , that react with phosphines, PR'3 = PPh3, PEt3, 1/2dppe, to yield and 2, respectively. (For the structures of these products see the Scheme.) The ionic compound 2>(ClO4)2 is formed from and dppe in the presence of NaClO4.The results obtained can be explained in terms of electrophilic attack of the metal on the aromatic rings.Structures for the new compounds are assigned on the basis of IR and NMR (1H, 13C, 31P) spectra.