10548-71-7

Basic information

• Product Name: 5-Pyperidin-1-yl-5-dezoxy-1,2-isopropylidene-alfa-D- xylofuranose
• Synonyms: 5-Pyperidin-1-yl-5-dezoxy-1,2-isopropylidene-alfa-D- xylofuranose;(3aR,5R,6S,6aR)-2,2-dimethyl-5-[(piperidin-1-yl)methyl]-tetrahydro-2H-furo[2,3-d][1,3]dioxol-6-ol
• CAS NO: 10548-71-7
• Molecular Formula: C13H23NO4
• Molecular Weight: 257.32602
• Mol File: 10548-71-7.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 5-Pyperidin-1-yl-5-dezoxy-1,2-isopropylidene-alfa-D- xylofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Pyperidin-1-yl-5-dezoxy-1,2-isopropylidene-alfa-D- xylofuranose(10548-71-7)
• EPA Substance Registry System: 5-Pyperidin-1-yl-5-dezoxy-1,2-isopropylidene-alfa-D- xylofuranose(10548-71-7)

Safety Data

• Hazardous Substances Data: 10548-71-7(Hazardous Substances Data)

Upstream product

• 110-89-4 piperidine 
• 6893-65-8 1,2-di-O-isopropylidene-5-O-tosyl-D-xylofuranose 

Relevant articles and documents

Enantioselective addition of diethylzinc to aldehydes using γ-aminoalcohols derived from α-D-xylose as new chiral catalysts

The enantioselective addition of diethylzinc to aldehydes using 1,2-isopropylidene-5-deoxy-5-dialkylamino-α-D-xylofuranoses derived from α-D-xylose as new catalysts provided the corresponding alcohols with 75-96% ee.

Catalytic enantioselective reactions. Part 9. 1,2-O-isopropylidene-5-deoxy-5-N,N-dialkyl (or -N-monoalkyl)amino-α-D-xylofuranose derivatives as highly effective chiral catalysts for enantioselective addition of diethylzinc to aliphatic and aromatic aldehydes

A series of new 1,2-O-isopropylidene-5-deoxy-5-N,N-dialkyl (or -N-monoalkyl)amino-α-D-xylofuranose derivatives have been prepared from α-D-xylose and their enantioselectivities as chiral catalysts for the addition of diethylzinc to aldehydes have been examined. Of the chiral catalysts examined, 5-deoxy-1,2-O-isopropylidene-5-morpholino-α-D-xylofuranose provides high enantioselectivity for aromatic and relatively hindered aliphatic aldehydes, and 5-deoxy-5-hexahydroazepinyl-1,2-O-isopropylidene-α-D-xylofuranose is highly effective for unhindered aliphatic aldehydes.