105516-47-0

Basic information

• Product Name: {[2-(4-Methylphenyl)-1-phenylvinyl]imino}triphenylphosphoran
• Synonyms: {[2-(4-Methylphenyl)-1-phenylvinyl]imino}triphenylphosphoran
• CAS NO: 105516-47-0
• Molecular Weight: 469.566
• Mol File: 105516-47-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {[2-(4-Methylphenyl)-1-phenylvinyl]imino}triphenylphosphoran(CAS DataBase Reference)
• NIST Chemistry Reference: {[2-(4-Methylphenyl)-1-phenylvinyl]imino}triphenylphosphoran(105516-47-0)
• EPA Substance Registry System: {[2-(4-Methylphenyl)-1-phenylvinyl]imino}triphenylphosphoran(105516-47-0)

Safety Data

• Hazardous Substances Data: 105516-47-0(Hazardous Substances Data)

Upstream product

• 100-47-0 benzonitrile 

Downstream Products

• 105516-59-4 Methyl-((E)-1-phenyl-2-p-tolyl-vinyl)-carbodiimide 
• 105516-81-2 Methyl-(7-methyl-3-phenyl-isoquinolin-1-yl)-amine 
• 105516-76-5 (7-Methyl-3-phenyl-isoquinolin-1-yl)-phenyl-amine 
• 105516-77-6 7-Methyl-3-phenyl-1-(p-tolylamino)isoquinoline 
• 105516-79-8 7-Methyl-3-phenyl-1-(p-chlorophenylamino)isoquinoline 
• 105516-78-7 (4-Methoxy-phenyl)-(7-methyl-3-phenyl-isoquinolin-1-yl)-amine 
• 105516-80-1 N-cyclohexyl-7-methyl-3-phenylisoquinolin-1-amine 
• 105516-68-5 2-[(Z)-Methylimino]-6-phenyl-5-p-tolyl-2,5-dihydro-pyridine-3,3,4,4-tetracarbonitrile 
• 105516-66-3 6-Phenyl-2-[(Z)-phenylimino]-5-p-tolyl-2,5-dihydro-pyridine-3,3,4,4-tetracarbonitrile 
• 105528-85-6 3,3,4,4-Tetracyano-6-phenyl-5-(p-tolyl)-2-(p-tolylimino)-2,3,4,5-tetrahydropyridine 
• 105516-67-4 3,3,4,4-Tetracyano-6-phenyl-5-(p-tolyl)-2-(p-methoxyphenylimino)-2,3,4,5-tetrahydropyridine 
• 105516-70-9 2-Cyclohexylamino-6-phenyl-5-p-tolyl-pyridine-3,3,4,4-tetracarbonitrile 
• 105516-56-1 (4-Methoxy-phenyl)-((E)-1-phenyl-2-p-tolyl-vinyl)-carbodiimide 
• 105516-55-0 ((E)-1-Phenyl-2-p-tolyl-vinyl)-p-tolyl-carbodiimide 

Relevant articles and documents

New Syntheses of Heterocycles with Vinyl- and Divinylcarbodiimides: Pyrroles, Triazoles, Pyrimidines, Pyrindines, Isoquinolines and Thiazolyl-isothiazoles

The title compounds 3 and 4 react with diazomethane either by loss or by retention of the diazo nitrogen, to afford 3,4-dihydro-2-imino-2H-pyrroles 6 and 10 or the vic-triazole 5, respectively.The structure of 5 has been established by X-ray diffraction analysis. - The addition of benzylidene methylamine or alicyclic enamines 9 to 4 results in the formation of partially hydrogenated pyrimidine 7, pyrindine 11a or isoquinoline 11b. - Thermolysis of 4 proceeds with spontaneous dehydrogenation, giving high yields of 1-(1-indolyl)isoquinolines 8. - The derivative 10a, when melted with sulfur, undergoes both dehydrogenation and sulfur insertion, whereby the hitherto unknown thiazolyl-isothiazole 13 is formed.Its structure has been elucidated by an X-ray diffraction analysis. - A synthesis of the imidazoisoquinoline derivative 16 is reported. - Key Words: Carbodiimides, vinyl-, divinyl- / Imidazoisoquinoline