1059018-91-5

Basic information

• Product Name: PERCHLORATE
• Synonyms: PERCHLORATE STANDARD;PERCHLORATE;PERCHLORATE IC STANDARD;PERCHLORATE ION CHROMATOGRAPHY STANDARD;6-Methyl-2,4-diphenyl-5,6,7,8-tetrahydro-chromenylium;2,6-ditert-butyl-N-phenylpyrylium-4-carboxamide;2-(oxamoylamino)ethylazanium;N-ethyl-1-azoniabicyclo[2.2.2]octane-4-carboxamide
• CAS NO: 1059018-91-5
• Molecular Formula: C22H21O+
• Molecular Weight: 301.40154
• Mol File: 1059018-91-5.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: PERCHLORATE(CAS DataBase Reference)
• NIST Chemistry Reference: PERCHLORATE(1059018-91-5)
• EPA Substance Registry System: PERCHLORATE(1059018-91-5)

Safety Data

• Hazardous Substances Data: 1059018-91-5(Hazardous Substances Data)

Usage

Chemical Description

Perchlorate is a salt that is used in rocket fuel and fireworks.

Description

Perchlorate is an inorganic compound known for its oxidizing properties and ability to inhibit the transport of iodide into the thyroid gland. It is colorless, odorless, and stable at room temperature, with high solubility in water. Perchlorate has been used in various applications, including rocket fuels, military operations, and as an ingredient in some consumer products.

Uses

Used in Aerospace Industry:
Perchlorate is used as an oxidant in solid rocket propellants for its high energy output and stability, making it essential for launching satellites and spacecraft.
Used in Military Applications:
In the military sector, perchlorate serves as a crucial component in ordnance and airbag deployment systems, ensuring the proper functioning of safety and defense mechanisms.
Used in Fireworks Industry:
Perchlorate is utilized as an oxidizing agent in fireworks, contributing to their bright and vibrant colors during displays.
Used in Automotive Industry:
Perchlorate compounds are employed in airbag deployment systems, ensuring the rapid and effective inflation of airbags during collisions to protect passengers.
Used in Fertilizer Industry:
Perchlorate is found in some commercial fertilizers, where it acts as an oxidant to promote plant growth and development.
Used in Consumer Products:
Perchlorate is detected in various consumer products such as bleach and sealing gaskets for food containers, where it serves as a stabilizing and oxidizing agent.

Clinical implications

There are some mutations in the NIS gene (SLC5A5) that cause hypothyroidism and thyroid dyshormonogenesis. Anti-NIS antibodies have been found in thyroid autoimmune diseases. Defects of the pendrin gene (PDS, SLC26A4) result in Pendred Syndrome associated with profound sensorineural hearing loss and a thyroid condition called goiter.

Origins of environmental perchlorates

Natural and anthropogenic sources. Five perchlorates are manufactured in large amounts as magnesium, potassium, ammonium, sodium, and lithium salts.

Exposure routes

From food (especially leafy green vegetable and milk) or drinking water, but not through the skin. For fetuses and infants, from the placenta, breast milk (or cow milk), infant formula, and baby food. The level in urine for children of 0.5–6 years of age is 2–3 times higher than for children 10 or older.

Upstream product

• 62483-45-8 tetramethylammonium chloroperchloratoaluminate 
• 13446-71-4 rubidium chlorate 
• 122380-54-5 Sn(tetra-p-tolylporphyrin)(ClO₄)2 
• 3811-04-9 potassium chlorate 
• 7601-90-3 perchloric acid 
• 12015-53-1 perchloric anhydride 
• 7616-94-6 perchloryl fluoride 
• 2816-43-5 triphenylgermane 
• 1449-63-4 trimethylgermane 
• 14380-61-1 hypochlorite 
• 14866-68-3 chlorate 
• 14998-27-7 chlorite 

Downstream Products

• 94780-63-9 {Os(PCH₃IC₆H₅)Cl(CO)2(P(C₆H₅)3)2}⁽¹⁺⁾*ClO₄^(1-)={Os(PCH₃IC₆H₅)Cl(CO)2(P(C₆H₅)3)2}ClO₄ 
• 42529-56-6 [Cu(C₂₄H₃₂N₄)(ClO₄)2] 
• 86773-55-9 [Mn(N,N'-propylenebis(salicylideneaminato))(H₂O)] perchlorate 
• 214333-26-3 [1,4-bis(diphenylphosphino)butane-P,P'](N,N'-diethyldithiocarbamato-S,S')nickel(II) perchlorate 
• 918445-81-5 [Pt(CHC6H5CH2NEt2-κC,κN)(N,N,N',N'-tetramethylethylenediamine)]ClO4 
• 957110-75-7 [Ru(1,10-phenanthroline)2(6-p-anisyl-2-(p-anisylamino)-3(4H)-p-anisylimine-9-methoxyphenazine(-H))]ClO₄ 
• 957110-69-9 [Ru(II)(2,2'-bipyridine)2(6-p-anisyl-2-(p-anisylamino)-3(4H)-p-anisylimine-9-methoxyphenazine(-H))]ClO₄ 

Relevant articles and documents

Intermediates in the oxidation of water by perxenate

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Effect of Axially Bound Anions on the Electroreduction of Tin(IV) Porphyrins in Tetrahydrofuran

The spectroscopic characterization and electrochemistry of SnL(X)2 is presented where L is the dianion of tetra-p-tolylporphyrin or tetra-m-tolylporphyrin and X is CIO4-, Br-, Cl-, F-, or OH-.In all cases, electroreduction leads to porphyrin ? anion radicals and dianions which were characterized in tetrahydrofuran by spectroelectrochemistry and e.s.r. spectroscopy.Dissociation of one CIO4- ion from SnL(CIO4)2 occurs before electroreduction of the complex but no dissociation is observed either before or after electroreduction of SnL(F)2 or SnL(OH)2.In contrast, one Br- ion dissociates after the first electron addition to SnL(Br)2 while one Cl- ion dissociates from SnCl(Cl)2 after the second electroreduction of this complex.

Trivalent germanium cations in solution

Reaction of R3GeH (R = Me, Ph) with trityl perchlorate produces free germylenium cations (R3Ge+) in dilute sulfolane solution. Conductivities, cryoscopic molecular weights, 35Cl line widths, and 35Cl