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10591-85-2

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10591-85-2 Usage

Uses

Different sources of media describe the Uses of 10591-85-2 differently. You can refer to the following data:
1. Accelerator for NR, SBR and NBR
2. Tetrabenzylthiuram Disulfide is one of the many lubricating oil for fork truck bearing; Also, it is derived from Dibenzylamine (D417505), which is a chemical contaminant in L-(+)-β-hydroxybutyrate, exhibits direct anticonvulsant actions in vivo.

Contact allergens

TBzTD is a rubber vulcanization accelerator.

Check Digit Verification of cas no

The CAS Registry Mumber 10591-85-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,5,9 and 1 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 10591-85:
(7*1)+(6*0)+(5*5)+(4*9)+(3*1)+(2*8)+(1*5)=92
92 % 10 = 2
So 10591-85-2 is a valid CAS Registry Number.

10591-85-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name dibenzylcarbamothioylsulfanyl N,N-dibenzylcarbamodithioate

1.2 Other means of identification

Product number -
Other names Tetrabenzylthiuramdisulfide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10591-85-2 SDS

10591-85-2Synthetic route

carbon disulfide
75-15-0

carbon disulfide

dibenzylamine
103-49-1

dibenzylamine

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

Conditions
ConditionsYield
Stage #1: carbon disulfide; dibenzylamine In water at 20 - 30℃; for 3h;
Stage #2: With dihydrogen peroxide for 1h; Reagent/catalyst; Temperature; Solvent; Reflux;
99.91%
Stage #1: carbon disulfide; dibenzylamine With haematoxylin In ethanol at 30 - 40℃; for 0.833333h;
Stage #2: In ethanol for 0.833333h; Reagent/catalyst; Solvent; Temperature; Irradiation;
98.51%
at 0 - 70℃; Temperature; Concentration;96.8%
N,N-dibenzyl dithiocarbamate
99-22-9

N,N-dibenzyl dithiocarbamate

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

Conditions
ConditionsYield
With oxygen In water at 20 - 30℃; under 750.075 Torr; for 0.666667h; Pressure; Flow reactor;99.9%
carbon disulfide
75-15-0

carbon disulfide

benzylamine
100-46-9

benzylamine

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

Conditions
ConditionsYield
With dihydrogen peroxide; sodium hydroxide at 35 - 40℃; for 3h;98.5%
dibenzyldithiocarbamate anion

dibenzyldithiocarbamate anion

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

Conditions
ConditionsYield
With sulfuric acid In dimethyl sulfoxide at 50℃; Temperature; Reagent/catalyst;97.3%
With sodium nitrate; hexacyanoferrate(III) In water; acetone at 25℃; Equilibrium constant; Rate constant; ΔH(excit.), ΔS(excit.), var. metal complexes and salts;
sodium dibenzyldithiocarbamate
55310-46-8

sodium dibenzyldithiocarbamate

C18H19NOS4

C18H19NOS4

A

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

B

sodium O-ethyl dithiocarbonate
140-90-9

sodium O-ethyl dithiocarbonate

Conditions
ConditionsYield
With sodium nitrate; C8MoN8(3-)*3Na(1+) In water; acetone at 25℃; Equilibrium constant; μ 0.2 mol/l;
sodium dibenzyldithiocarbamate
55310-46-8

sodium dibenzyldithiocarbamate

C22H28N2S4

C22H28N2S4

A

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

B

sodium N,N'-diisopropyldithiocarbamate
4092-82-4

sodium N,N'-diisopropyldithiocarbamate

Conditions
ConditionsYield
With sodium nitrate; potassium hexacyanoferrate(III) In water; acetone at 25℃; Rate constant; Equilibrium constant; μ 0.2 mol/l;
dibenzyldithiocarbamate radical

dibenzyldithiocarbamate radical

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

Conditions
ConditionsYield
With sodium nitrate In water; acetone at 25℃; Equilibrium constant;
N,N-iminodiethanoldithiocarbamic acid
1528-72-9

N,N-iminodiethanoldithiocarbamic acid

hexacyanoferrate(III)

hexacyanoferrate(III)

A

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

B

hexacyanoferrate(II)

hexacyanoferrate(II)

Conditions
ConditionsYield
With sodium nitrate In water; acetone Kinetics; Electrochem. Process; 25°C, different acetone/H2O mixtures (30, 40, 50, 80, 90% acetone);
With sodium nitrate In water Kinetics; Electrochem. Process; 25°C;
octacyanomolybdate(V)

octacyanomolybdate(V)

N,N-dibenzyl dithiocarbamate
99-22-9

N,N-dibenzyl dithiocarbamate

A

octacyanomolybdate(IV) ion

octacyanomolybdate(IV) ion

B

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

Conditions
ConditionsYield
With sodium nitrate In dimethyl sulfoxide Electrochem. Process; 25°C, 30% aq.acetone;
With sodium nitrate In water; acetone Kinetics; Electrochem. Process; 25°C, 30% aq.acetone, at different ph (9-12);
N,N-dibenzyl dithiocarbamate
99-22-9

N,N-dibenzyl dithiocarbamate

hexacyanoferrate(III)

hexacyanoferrate(III)

A

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

B

hexacyanoferrate(II)

hexacyanoferrate(II)

Conditions
ConditionsYield
With sodium nitrate In water; acetone Kinetics; Electrochem. Process; 25°C, 30% aq.acetone, at different pH (9-12);
potassium dibenzyldithiocarbamate trihydrate
20293-68-9

potassium dibenzyldithiocarbamate trihydrate

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

Conditions
ConditionsYield
With hydrogenchloride; sodium nitrite In methanol; water at 0 - 5℃;
With hydrogenchloride; sodium nitrite In methanol; ethanol; water Cooling;
indole
120-72-9

indole

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

1H-indol-1-yl dibenzylcarbamodithioate

1H-indol-1-yl dibenzylcarbamodithioate

Conditions
ConditionsYield
With potassium tert-butylate In 1,2-dichloro-ethane at 20℃; for 1h;83%
With potassium tert-butylate In 1,2-dichloro-ethane at 25℃; for 1h;83%
bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

trimethylamine-gallane adduct
19528-13-3

trimethylamine-gallane adduct

tris(N,N-dibenzyldithiocarbamato)gallium(III) complex

tris(N,N-dibenzyldithiocarbamato)gallium(III) complex

Conditions
ConditionsYield
In toluene under Ar; std. Schlenk techniques; soln. of Me3N*GaH3 added gradually to soln. of (Bz2NC(S)S)2 at room temp.; soln. allowed to stir at room temp. for 16 h; filtered; solvent vol. reduced in vac.; recrystd. at room temp.; elem. anal.;69%
bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

dibenzyldithiocarbamate radical

dibenzyldithiocarbamate radical

Conditions
ConditionsYield
With sodium nitrate In water; acetone at 25℃; Equilibrium constant;
bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

N,N-dibenzyl-1,1,1-trifluoromethanamine
143490-28-2

N,N-dibenzyl-1,1,1-trifluoromethanamine

Conditions
ConditionsYield
With silver fluoride In various solvent(s) at 20℃; for 3h;
bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

C15H14FNS

C15H14FNS

Conditions
ConditionsYield
With silver fluoride In various solvent(s) at 20℃; for 0.5h;
bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

tetramethylammonium trifluoromethyltellurate(0)

tetramethylammonium trifluoromethyltellurate(0)

tetramethylammonium trifluoromethylbis(dibenzyldithiocarbamato)tellurate(II)

tetramethylammonium trifluoromethylbis(dibenzyldithiocarbamato)tellurate(II)

Conditions
ConditionsYield
In acetonitrile at 20℃; for 1h;
C2F5Te(1-)*C4H12N(1+)

C2F5Te(1-)*C4H12N(1+)

bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

tetramethylammonium pentafluoroethylbis(dibenzyldithiocarbamato)tellurate(II)

tetramethylammonium pentafluoroethylbis(dibenzyldithiocarbamato)tellurate(II)

Conditions
ConditionsYield
In acetonitrile at 20℃; for 1h;
bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

C16H14F3NS2Te
942626-67-7

C16H14F3NS2Te

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: acetonitrile / 1 h / 20 °C
2: Ag[BF4] / acetonitrile / 0.5 h / 20 °C
View Scheme
bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

C17H14F5NS2Te

C17H14F5NS2Te

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: acetonitrile / 1 h / 20 °C
2: Ag[BF4] / acetonitrile / 0.5 h / 20 °C
View Scheme
bis(dibenzylthiocarbamoyl)disulfide
10591-85-2

bis(dibenzylthiocarbamoyl)disulfide

4,4-Dibenzyl-thiosemicarbazid
21076-54-0

4,4-Dibenzyl-thiosemicarbazid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: NaCN / ethanol / Heating
2: N2H4*H2O / ethanol / Heating
View Scheme

10591-85-2Relevant articles and documents

Photocatalytic H2-Evolution by Homogeneous Molybdenum Sulfide Clusters Supported by Dithiocarbamate Ligands

Fontenot, Patricia R.,Shan, Bing,Wang, Bo,Simpson, Spenser,Ragunathan, Gayathri,Greene, Angelique F.,Obanda, Antony,Hunt, Leigh Anna,Hammer, Nathan I.,Webster, Charles Edwin,Mague, Joel T.,Schmehl, Russell H.,Donahue, James P.

, p. 16458 - 16474 (2019)

Irradiation at 460 nm of [Mo3(μ3-S)(μ2-S2)3(S2CNR2)3]I ([2a]I, R = Me; [2b]I, R = Et; [2c]I, R = iBu; [2d]I, R = CH2C6H5) in a mixed aqueous-polar organic medium with [Ru(bipy)3]2+ as photosensitizer and Et3N as electron donor leads to H2 evolution. Maximum activity (300 turnovers, 3 h) is found with R = iBu in 1:9 H2O:MeCN; diminished activity is attributed to deterioration of [Ru(bipy)3]2+. Monitoring of the photolysis mixture by mass spectrometry suggests transformation of [Mo3(μ3-S)(μ2-S2)3(S2CNR2)3]+ to [Mo3(μ3-S)(μ2-S)3(S2CNR2)3]+ via extrusion of sulfur on a time scale of minutes without accumulation of the intermediate [Mo3S6(S2CNR2)3]+ or [Mo3S5(S2CNR2)3]+ species. Deliberate preparation of [Mo3S4(S2CNEt2)3]+ ([3]+) and treatment with Et2NCS21- yields [Mo3S4(S2CNEt2)4] (4), where the fourth dithiocarbamate ligand bridges one edge of the Mo3 triangle. Photolysis of 4 leads to H2 evolution but at ~25% the level observed for [Mo3S7(S2CNEt2)3]+. Early time monitoring of the photolyses shows that [Mo3S4(S2CNEt2)4] evolves H2 immediately and at constant rate, while [Mo3S7(S2CNEt2)3]+ shows a distinctive incubation prior to a more rapid H2 evolution rate. This observation implies the operation of catalysts of different identity in the two cases. Photolysis solutions of [Mo3S7(S2CNiBu2)3]+ left undisturbed over 24 h deposit the asymmetric Mo6 cluster [(iBu2NCS2)3(μ2-S2)2(μ3-S)Mo3](μ3-S)(μ3-η2,η1-S′,η1-S″-S2)[Mo3(μ2-S)3(μ3-S)(S2CNiBu2)2(μ2-S2CNiBu2)] in crystalline form, suggesting that species with this hexametallic composition and core topology are the probable H2-evolving catalysts in photolyses beginning with [Mo3S7(S2CNR2)3]+. When used as solvent, N,N-dimethylformamide (DMF) suppresses H2-evolution but to a greater degree for [Mo3S4(S2CNEt2)4] than for [Mo3S7(S2CNEt2)3]+. Recrystallization of [Mo3S4(S2CNEt2)4] from DMF affords [Mo3S4(S2CNEt2)4(η1,κO-DMF)] (5), implying that inhibition by DMF arises from competition for a Mo coordination site that is requisite for H2 evolution. Computational assessment of [Mo3S4(S2CNMe2)3]+ following addition of 2H+ and 2e- suggests a Mo(H)-μ2(SH) intermediate as the lowest energy species for H2 elimination. An analogous pathway may be available to the Mo6 cluster via dissociation of one end of the μ2-S2CNR2 ligand, a known hemilabile ligand type, in the [Mo3S4]4+ fragment.

Method for preparing tetrabenzyl thiuram disulfide

-

Paragraph 0008; 0023-0026; 0027-0031; 0032-0045, (2021/11/21)

The invention belongs to the technical field of rubber auxiliary production, and relates to a method for preparing a disulphide tetrabenzyl thiuram disulfide. The method comprises the following steps: sequentially adding water, an aqueous sodium hydroxide solution and dibenzylamine in a reactor, adding a dispersing agent, and then dropwise adding carbon disulfide to perform condensation reaction to obtain the dibenzyldithioformate solution. The sodium dibenzyldithioformate solution is subjected to oxidation reaction and then filtered and dried to obtain a thiurylthiuram disulfide. In the condensation reaction process, the dispersing agent is added, the reaction system forms a uniform state, the reaction process is carried out in a uniform system, two-phase reaction is avoided when carbon disulfide is added dropwise in the prior art, and the reaction effect is poor. COD In the waste water is low, easily waste water treatment. The obtained disulfide tetrabenzylthiuram product has the appearance of white powder and the purity 98% or more.

Continuous-flow step-economical synthesis of thiuram disulfidesviavisible-light photocatalytic aerobic oxidation

Xu, Hao-Xing,Zhao, Ze-Run,Patehebieke, Yeersen,Chen, Qian-Qian,Fu, Shun-Guo,Chang, Shuai-Jun,Zhang, Xu-Xu,Zhang, Zhi-Liang,Wang, Xiao

supporting information, p. 1280 - 1285 (2021/02/26)

A continuous-flow photocatalytic synthesis of the industrially important thiuram disulfides has been developed, utilizing O2as the oxidant and Eosin Y as the photoredox catalyst. This highly atom- and step-economical method features much reduced reaction time as well as excellent product yield and purity, making it a sustainable and potentially scalable process for industrial production.

Disulfiram as a potent metallo-β-lactamase inhibitor with dual functional mechanisms

Chen, Cheng,Li, Jia-Qi,Sun, Le-Yun,Wu, Lin-Yu,Yang, Ke-Wu

supporting information, p. 2755 - 2758 (2020/03/17)

We report a promising NDM-1 inhibitor, disulfiram, which can covalently bind to NDM-1 by forming an S-S bond with the Cys208 residue. Its copper-containing metabolite in vivo, Cu(DTC)2, also inactivated NDM-1 through oxidizing the Zn(ii) thiolate site of the enzyme, therefore exhibiting dual functional inhibitory potential against B1 and B2 subclass MβLs.

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