105987-36-8

Basic information

• Product Name: Trimethyl-[(S)-4-methyl-1-((S)-1-methyl-but-3-enyl)-cyclohex-3-enyloxy]-silane
• Synonyms: Trimethyl-[(S)-4-methyl-1-((S)-1-methyl-but-3-enyl)-cyclohex-3-enyloxy]-silane
• CAS NO: 105987-36-8
• Molecular Weight: 252.472
• Mol File: 105987-36-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Trimethyl-[(S)-4-methyl-1-((S)-1-methyl-but-3-enyl)-cyclohex-3-enyloxy]-silane(CAS DataBase Reference)
• NIST Chemistry Reference: Trimethyl-[(S)-4-methyl-1-((S)-1-methyl-but-3-enyl)-cyclohex-3-enyloxy]-silane(105987-36-8)
• EPA Substance Registry System: Trimethyl-[(S)-4-methyl-1-((S)-1-methyl-but-3-enyl)-cyclohex-3-enyloxy]-silane(105987-36-8)

Safety Data

• Hazardous Substances Data: 105987-36-8(Hazardous Substances Data)

Upstream product

• 106035-80-7 (1R,3S,6S)-3-Isopropenyl-6-methyl-7-oxa-bicyclo[4.1.0]heptan-3-ol 
• 6909-30-4 (1S,2R,4R)-limonene-1,2-epoxide 
• 105987-22-2 (S)-3-((S)-4-Methyl-1-trimethylsilanyloxy-cyclohex-3-enyl)-butan-1-ol 
• 73069-45-1 (-)-(S)-p-mentha-1,8-dien-4-ol 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 105987-35-7 (S)-3-((S)-4-Methyl-1-trimethylsilanyloxy-cyclohex-3-enyl)-butyraldehyde 

Downstream Products

• 15352-77-9 (+)-(4S,8S)-β-bisabolol 
• 105987-37-9 (S)-4-((S)-4-Methyl-1-trimethylsilanyloxy-cyclohex-3-enyl)-pentan-1-ol 

Relevant articles and documents

The Absolute Configuration of β-Bisabolol

From bergamot oil (Citrus bergamia RISSO), (-)-(4S,8R)-8-epi-α-bisabolol (2) and (-)-(4R,8S)-4-epi-β-bisabolol (3) were isolated.The absolute configuration of their stereoisomers 4 and 5 was established by an enantioselective synthesis starting from (-)-(S)-p-mentha-1,8-dien-4-ol.