106727-56-4

Basic information

• Product Name: benzyl N-acetoacetylglycinate
• CAS NO: 106727-56-4
• Molecular Weight: 249.266
• Mol File: 106727-56-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: benzyl N-acetoacetylglycinate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl N-acetoacetylglycinate(106727-56-4)
• EPA Substance Registry System: benzyl N-acetoacetylglycinate(106727-56-4)

Safety Data

• Hazardous Substances Data: 106727-56-4(Hazardous Substances Data)

Upstream product

• 674-82-8 4-methyleneoxetan-2-one 
• 1738-76-7 glycine benzyl ester p-toluenesulfonic acid salt 

Downstream Products

• 106727-58-6 3-acetyl-1-(benzyloxycarbonylmethyl)-4-hydroxy-2-pyridone 
• 106727-61-1 (3-{1-[(E)-Benzylimino]-ethyl}-4-hydroxy-2-oxo-2H-pyridin-1-yl)-acetic acid benzyl ester 
• 106727-57-5 3-benzylamino-N-(benzyloxycarbonylmethyl)-2-butenamide 

Relevant articles and documents

SYNTHESIS OF 1,3-DIOXIN-4-ONES AND THEIR USE IN SYNTHESIS. XI. 2,2-DIMETHYL-1,3-DIOXIN-4-ONE AS A SYNTHETIC EQUIVALENT OF FORMYLKETENE: SYNTHESIS OF HETEROCYCLIC COMPOUNS

Cycloaddition of formylketene generated in situ by thermolysis of 2,2-dimethyl-1,3-dioxin-4-one with N-benzhydrylidenebenzylamine yields 3-benzyl-2,2-diphenyl-1,3-oxazin-4-one.Analogous reactions with a carbodiimide, cyanamide, and keteneacetal afford the corresponding 4 + 2 cycloadducts.Reaction of formylketene with 3-amino-2-butenamides affords 4-hydroxy-2-pyridones having a C-2 unit at the 3-position.Keywords: 1,3-dioxin-4-one;formylketene; cycloaddition;1,3-oxazin-4-one; 4-pyrone; 3-acetyl-4-hydroxy-2-pyridone; thermolysis; uracil derivative.