106727-86-0Relevant articles and documents
Design and characterization of 4,5-bis(diarylamino)phthalic acid diesters as a new class of fluorophores exhibiting efficient blue emission in the solid state
Shimizu, Masaki,Tamagawa, Tomokazu
, p. 291 - 295 (2015)
We developed 4,5-bis(diarylamino)phthalic acid diesters as blue fluorophores exhibiting efficient photoluminescence in powder and in a thin film of pol(methyl methacrylate). Increasing the electron-donating nature of the substituents in the para positions
Synthesis of Core-Modified Third-Generation Light-Driven Molecular Motors
Berrocal, José Augusto,Pfeifer, Lukas,Heijnen, Dorus,Feringa, Ben L.
, p. 10670 - 10680 (2020/09/18)
The synthesis and characterization of a series of light-driven third-generation molecular motors featuring various structural modifications at the central aromatic core are presented. We explore a number of substitution patterns, such as 1,2-dimethoxybenzene, naphthyl, 1,2-dichlorobenzene, 1,1′:2′,1″-terphenyl, 4,4″-dimethoxy-1,1':2′,1″-terphenyl, and 1,2-dicarbomethoxybenzene, considered essential for designing future responsive systems. In many cases, the synthetic routes for both synthetic intermediates and motors reported here are modular, allowing for their post-functionalization. The structural modifications introduced in the core of the motors result in improved solubility and a bathochromic shift of the absorption maxima. These features, in combination with a structural design that presents remote functionalization of the stator with respect to the fluorene rotors, make these novel motors particularly promising as light-responsive actuators in covalent and supramolecular materials.
The organic EL element emitting material
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Paragraph 0081; 0082, (2016/12/12)
PROBLEM TO BE SOLVED: To provide a compound for a light-emitting material having high light-emitting efficiency even in a solid state, and to provide the light-emitting material using the compound, and an organic EL element.SOLUTION: A bis(diarylamino)pht