1072234-72-0Relevant articles and documents
Palladium-catalyzed enantioselective oxidation of chiral secondary alcohols: Access to both enantiomeric series
Ebner, David C.,Trend, Raissa M.,Genet, Cedric,McGrath, Matthew J.,O'Brien, Peter,Stoltz, Brian M.
scheme or table, p. 6367 - 6370 (2009/03/11)
(Chemical Equation Presented) Rapid resolution: A new catalyst system for the oxidative kinetic resolution of secondary alcohols leads to dramatic rate increases. This system allows the use of a diamine to provide access to either enantiomer of a range of alcohols with good selectivity factors (see scheme). This method has been applied to the formal total synthesis of (-)-amurensinine.