1074-56-2

Basic information

• Product Name: 4-CHLOROPHENYLVINYLETHER
• Synonyms: 4-CHLOROPHENYLVINYLETHER;(p-Chlorophenyl)vinyl ether;1-(Vinyloxy)-4-chlorobenzene;Vinyl(4-chlorophenyl) ether
• CAS NO: 1074-56-2
• Molecular Formula: C₈H₇ClO
• Molecular Weight: 154.59
• Mol File: 1074-56-2.mol
• Article Data: 9

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-CHLOROPHENYLVINYLETHER(CAS DataBase Reference)
• NIST Chemistry Reference: 4-CHLOROPHENYLVINYLETHER(1074-56-2)
• EPA Substance Registry System: 4-CHLOROPHENYLVINYLETHER(1074-56-2)

Safety Data

• Hazardous Substances Data: 1074-56-2(Hazardous Substances Data)

Usage

General Description

4-Chlorophenylvinylether is a chemical compound with the molecular formula C8H7ClO. It is a colorless liquid with a pungent odor, and it is mainly used as an intermediate for the synthesis of pharmaceuticals, agrochemicals, and other organic compounds. It is classified as a vinyl ether, meaning it contains a vinyl group (C=C) bonded to an ether functional group (C-O-C). 4-Chlorophenylvinylether is also known for its reactivity in various chemical reactions, such as nucleophilic substitution and polymerization, making it a versatile building block for the production of a wide range of organic compounds. However, it should be handled with care due to its potential health hazards and reactivity with certain chemicals.

Upstream product

• 106-48-9 4-chloro-phenol 
• 108-05-4 vinyl acetate 
• 3284-79-5 3-(4-chlorophenoxy)propionic acid 
• 106-93-4 ethylene dibromide 
• 34649-14-4 p-vinyloxybenzenediazonium chloride 
• 13001-28-0 1-chloro-4-(2-chloroethoxy)-benzene 
• 75-01-4 chloroethylene 
• 1193-00-6 sodium 4-chlorophenolate 
• 2033-76-3 1-(2-bromoethoxy)-4-chlorobenzene 

Downstream Products

• 17902-38-4 Dichlormethyl-<2-(4-chlorphenoxy)-ethyl>-silan 
• 18141-07-6 Dichlor-<4-chlorphenoxy>-methylsilan 
• 17204-68-1 1-chloro-4-cyclopropoxybenzene 
• 19035-40-6 1,1-Dichlor-2-(4-chlor-phenoxy)-cyclopropan 
• 91822-40-1 1,2,3,4,7,7-Hexachlor-5-(4-chlor-phenoxy)-bicyclo <2.2.1> hepten-(2) 
• 79798-63-3 1-Chloro-4-(2-ethoxy-cyclobutoxy)-benzene 
• 122023-60-3 4-chlorophenoxyoxirane 
• 117951-06-1 2-Chloro-2-(4-chloro-phenoxy)-ethanesulfonyl fluoride 
• 89249-64-9 3-Benzhydryl-5-(4-chloro-phenoxy)-4,5-dihydro-isoxazole 
• 120166-38-3 1-chloro-1-p-chlorophenoxy-2-(p-bromophenylseleno)ethane 
• 111862-31-8 1-Chloro-4-(1-chloro-2-thiocyanato-ethoxy)-benzene 
• 34573-93-8 1,1,2,2-Tetracyano-3-(4'-chloro)-phenoxycyclobutan 
• 75269-49-7 2-phenyl-3-benzoyl-5-(p-chlorophenoxy)isoxazolidine 
• 3769-34-4 (4-Chlor-phenyl)-(1,2-dichlor-aethyl)-aether 

Relevant articles and documents

A mild and efficient protocol for the conversion of carboxylic acids to olefins by a catalytic decarbonylative elimination reaction

A new method for the conversion of aliphatic carboxylic acids to olefins under unprecedented mild conditions is disclosed, wherein the carboxylic acids are converted in situ with pivalic anhydride to the mixed anhydrides, which regioselectively add to a PdCl2-DPE-Phos catalyst. At a temperature of only 110°C, smooth decarbonylation and β-hydride elimination occur, and the corresponding olefins along with CO, CO2 and pivalic acid are liberated.

Reductive C-O, C-N, and C-S Cleavage by a Zirconium Catalyzed Hydrometalation/β-Elimination Approach

A zirconium catalyzed reductive cleavage of Csp3 and Csp2 carbon-heteroatom bonds is reported that makes use of a tethered alkene functionality as a traceless directing group. The reaction is successfully demonstrated on C-O, C-N, and C-S bonds and proposed to proceed via a hydrozirconation/β-heteroatom elimination sequence of an in situ formed zirconium hydride catalyst. The positional isomerization of the catalyst further enables the cleavage of homoallylic ethers and the removal of terminal allyl and propargyl groups.

Solid-Phase synthesis of aryl vinyl ethers based on polystyrenesupported aβ-phenylselenoethanol

A novel facile solid-phase organic synthesis of aryl vinyl ethers by reaction of polystyrene-supported β-phenylselenoethanol with phenols under Mitsunobu conditions and subsequent oxidation-elimination with 30% hydrogen peroxide has been developed. The ad