1075708-64-3Relevant articles and documents
NAP ether mediated intramolecular aglycon delivery: A unified strategy for 1,2-cis-glycosylation
Ishiwata, Akihiro,Munemura, Yuichi,Ito, Yukishige
experimental part, p. 4250 - 4263 (2009/04/10)
A methodology directed towards the stereoselective construction of 1,2-cis-glycosides through naphthylmethyl (NAP) ether mediated intramolecular aglycon derivery (IAD) has been developed. Stereospecific constructions of various 1,2-cis linkages, as in β-mannopyrano-, β-arabinofurano-, and α-glucopyranosides, were achieved through NAP-IAD. This methodology was successfully applied to the synthesis of Glcα(1→2)- Glcα(1→3)-Glcα(1→3)Man (Glc3Man1), the nonreducing terminal structure of the tetradecasaccharide Glc 3Man9GlcNAc2, a common precursor of all N-linked glycans. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.