1076-44-4

Basic information

• Product Name: Lithium,(2,3,4,5,6-pentafluorophenyl)-
• Synonyms: Lithium,(pentafluorophenyl)- (7CI,8CI,9CI); Benzene, pentafluoro-, lithium complex; Pentafluorophenyllithium; Perfluorophenyllithium
• CAS NO: 1076-44-4
• Molecular Formula: C₆F₅Li
• Molecular Weight: 174.00
• Mol File: 1076-44-4.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Lithium,(2,3,4,5,6-pentafluorophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Lithium,(2,3,4,5,6-pentafluorophenyl)-(1076-44-4)
• EPA Substance Registry System: Lithium,(2,3,4,5,6-pentafluorophenyl)-(1076-44-4)

Safety Data

• Hazard Codes: 3:
• Safety Statements: 2O and F−. See also FLUORIDES and LITHIUM COMPOUNDS." target="_blank">Explodes on contact with water or deuterium oxide. W
• Hazardous Substances Data: 1076-44-4(Hazardous Substances Data)

Upstream product

• 344-04-7 bromopentafluorobenzene 
• 363-72-4 Pentafluorobenzene 
• 865-47-4 potassium tert-butylate 
• 771-56-2 2,3,4,5,6-pentafluorotoluene 
• 879-05-0 2,3,4,5,6-pentafluorophenylmagnesium bromide 
• 593-81-7 trimethylamine hydrochloride 
• 5882-44-0 N,N-dimethylaniline hydrochloride 
• 109-72-8 n-butyllithium 
• 827-15-6 1,2,3,4,5-pentafluoro-6-iodobenzene 
• 1206-46-8 trimethyl(pentafluorophenyl)silane 
• 917-54-4 methyllithium 
• 973-17-1 bis(pentafluorophenyl)mercury(II) 
• 13888-78-3 di-(pentafluoro phenyl) methylsilane 
• 13888-77-2 (pentafluorophenyl)dimethylsilane 

Downstream Products

• 21190-47-6 Bis-(pentafluor-phenyl)-methyl-carbinol 
• 25959-54-0 Trifluormethyl-bis-(pentafluor-phenyl)-carbinol 
• 25798-77-0 2-Chloro-1,1-bis-pentafluorophenyl-ethanol 
• 25798-78-1 2-Bromo-1,1-bis-pentafluorophenyl-ethanol 
• 827-08-7 1,2-dibromo-3,4,5,6-tetrafluorobenzene 
• 1944-05-4 2,3,4,5,6-pentafluoro-α-phenylbenzenemethanol 
• 34126-28-8 tetrakis(pentafluorophenyl)sulfur 
• 23673-50-9 N-2,3,4,5-Tetrafluor-benzyl-N-methylanilin 
• 173681-59-9 1-(4-tert-Butyl-2-iodo-phenyl)-2,2,2-trifluoro-1-pentafluorophenyl-ethanol 
• 19555-07-8 Decafluorobenzil 
• 19349-34-9 1,6-Bis-(pentafluorphenyl)-hexandion-(1,6) 
• 30780-33-7 (4-Pentafluorobenzoyl-phenyl)-pentafluorophenyl-methanone 
• 1109-15-5 tris(pentafluorophenyl)borate 
• 973-18-2 bis(perfluorophenyl) selenide 

Relevant articles and documents

Synthesis and characterization of acetonitrile-ligated transition-metal complexes with tetrakis(pentafluorophenyl)borate as counteranions

Complexes with the general formula [MII(NCCH3) 6][TPFB]2 [M = Cr, Fe, Co, Ni, Cu, Zn, (TPFB)- = tetrakis-(pentafluorophenyl)borate] were synthesized and characterized both in the solid state and in solution. According to the spectroscopic data, [TPFB] can be considered as a truly noncoordinating anion. The NCCH3 ligands are lost if the samples are kept at room temperature for extended periods of time. Thermolysis leads to the loss of the NCCH3 ligands and decomposition of the anion above 100°C with the formation of MF2. It has to be noted that distortion of the geometries of the CuII, ZnII and CrII complexes occurs, as evidenced by infrared spectroscopy. The complexes can be easily prepared and obtained in high yields and are moderately sensitive to air. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.

Pyridylamino IVB group binuclear metal complex and preparation and application thereof

The invention relates to a pyridylamino IVB group binuclear metal complex and the preparation and the application thereof. The structure of the pyridylamino IVB group binuclear metal complex is shownas a formula I, and the pyridylamino IVB group binuclear

donor-acceptor oligogermanes: Synthesis, structure, and electronic properties

A series of oligogermanes, (Me3Si)3GeGeCl 3, (C6F5)3GeGePh3, (C6F5)3GeGe(p-Tol)3, and (C 6F5)2Ge[Ge(p-Tol)3]2, containing substituents with different electronic properties at neighboring germanium atoms were synthesized. According to X-ray diffraction studies, UV/visible spectroscopy, and quantum chemical calculations, these donor-acceptor oligogermanes are characterized by energies of electronic transitions lower than those for other similar compounds.