1080-02-0

Basic information

• Product Name: 4-NITROBENZENEAZOMALONONITRILE
• Synonyms: 4-NITROBENZENEAZOMALONONITRILE;2-(4-Nitrophenyl)hydrazone Propanone;Acetone 4-Nitrophenylhydrazone
• CAS NO: 1080-02-0
• Molecular Formula: C₉H₁₁N₃O₂
• Molecular Weight: 279.2138
• Product Categories: Aromatics Compounds;Aromatics
• Mol File: 1080-02-0.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• Solubility: Chloroform, Dichloromethane, Ethyl Acetate
• CAS DataBase Reference: 4-NITROBENZENEAZOMALONONITRILE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-NITROBENZENEAZOMALONONITRILE(1080-02-0)
• EPA Substance Registry System: 4-NITROBENZENEAZOMALONONITRILE(1080-02-0)

Safety Data

• Hazardous Substances Data: 1080-02-0(Hazardous Substances Data)

Usage

Description

4-Nitrobenzeneazomalononitrile, with the CAS number 1080-02-0, is a yellow solid compound that is widely utilized in the field of organic synthesis. It is known for its unique chemical properties that make it a valuable component in various chemical reactions and processes.

Uses

Used in Organic Synthesis:
4-Nitrobenzeneazomalononitrile is used as a key intermediate in the synthesis of various organic compounds. Its chemical structure allows it to participate in a range of reactions, such as condensation, substitution, and addition reactions, leading to the formation of diverse organic molecules.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, 4-Nitrobenzeneazomalononitrile is used as a building block for the development of new drugs. Its unique chemical properties enable the creation of novel drug candidates with potential therapeutic applications.
Used in Dye Industry:
4-Nitrobenzeneazomalononitrile is also utilized in the dye industry for the production of various types of dyes. Its chemical structure allows for the synthesis of dyes with specific color properties and characteristics, making it a valuable component in the development of new dye products.
Used in Chemical Research:
In the field of chemical research, 4-Nitrobenzeneazomalononitrile serves as an important compound for studying various chemical reactions and mechanisms. Its unique properties make it an ideal candidate for exploring new reaction pathways and understanding the underlying chemistry involved.

Upstream product

• 32795-85-0 2-methoxyphenyl 4'-nitrophenyl ether 
• 7803-57-8 hydrazine hydrate 
• 456-27-9 4-nitrobenzenediazonium tetrafluoroborate 
• 3958-63-2 lithium 2-nitropropane 
• 38825-66-0 1-(propan-2-ylidene)-2-(4-oxo-thiazolidin-2-ylidene)hydrazine 
• 100-16-3 4-nitrophenylhydrazone 
• 87976-53-2 2,2-bis(2,2-dimethyl-1,3-dioxolan-4-ylmethoxy)propane 
• 87976-54-3 2-(2,2-dimethyl-1,3-dioxolan-4-ylmethoxy)-2-methoxypropane 
• 67-64-1 acetone 

Downstream Products

• 19958-48-6 2,4,4',6-tetranitohydrazobenzene 
• 92594-75-7 (1-Isothiocyanato-1-methyl-ethyl)-(4-nitro-phenyl)-diazene 
• 92594-68-8 (1-Isocyanato-1-methyl-ethyl)-(4-nitro-phenyl)-diazene 
• 66661-64-1 C₁₃H₁₅N₃O₄ 
• 13994-43-9 pyruvaldehyde bis-(4-nitro-phenylhydrazone) 
• 91027-25-7 5,5-Dimethyl-2-(4-nitro-phenyl)-[1,2,4]triazolidine-3-thione 
• 73150-88-6 5,5-dimethyl-2-(4-nitro-phenyl)-[1,2,4]triazolidin-3-one 
• 554-00-7 2,4-Dichloroaniline 
• 7013-75-4 pyruvaldehyde-2-(4-nitro-phenylhydrazone) 

Relevant articles and documents

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REACTIONS OF PENTAFLUOROPHENYLHYDRAZINE AND SOME OF ITS N'-ACYL DERIVATIVES WITH COMPOUNDS CONTAINING A TRICHLOROMETHYL GROUP IN THE PRESENCE OF ALUMUNIUM CHLORIDE

The reactions of pentafluorophenylhydrazine and also of N'-benzoyl-, N'-pentafluorobenzoyl-, and N'-acetylpentafluorophenylhydrazines and decafluorohydrazobenzene with CCl3R (R=Cl, C6H5, C6F5) in the presence of aluminium chloride were investigated.The main products from the reaction of pentafluorophenylhydrazine with the reagents were N-pentafluorophenylhydrazonodichloromethane and N-pentafluorophenylhydrazonoaryl chlorides.Derivatives of 1,3,4-oxadiazol-2-in-5-one were formed in the reactions of N'-acylpentafluorophenylhydrazines with carbon tetrachloride in the pres ence of aluminium chloride.When heated with carbon tetrachloride and aluminium chloride, decafluorohydrazobenzene disproportionates with the formation of decafluoroazobenzene and pentafluoroaniline.

Synthesis, spectral and structural studies, and an evaluation of the hydrogen bonding of some phenylhydrazones

A series of 46 phenylhydrazones, some novel, containing a variety of structural types has been synthesised. These have been studied by 1H n.m.r. and i.r. spectroscopy with respect to potential inter- and intra-molecular hydrogen bonding. ortho-Nitro or -carbonyl groups form strong hydrogen bonds to the imino-group which are readily observed by 1H n.m.r. but not by i.r. spectroscopy. 'Terminal' carbonyl groups also form strong hydrogen bonds to the imino-group and these can be detected by both i.r. and 1H n.m.r. spectroscopy. When both ortho-nitro- or -carbonyl groups and 'terminal' carbonyl groups are present the imino hydrogen atom is doubly hydrogen bonded and this is apparent in the 1H n.m.r. spectrum. The formation of an intramolecular hydrogen bond in the phenylhydrazone prevents the formation of an intermolecular hydrogen bond between the phenylhydrazone and a polar solvent.