1080-41-7Relevant articles and documents
Silver-Catalyzed Oxidative C(sp3)?P Bond Formation through C?C and P?H Bond Cleavage
Li, Lili,Huang, Wenbin,Chen, Lijin,Dong, Jiaxing,Ma, Xuebing,Peng, Yungui
supporting information, p. 10539 - 10544 (2017/08/22)
The silver-catalyzed oxidative C(sp3)?H/P?H cross-coupling of 1,3-dicarbonyl compounds with H-phosphonates, followed by a chemo- and regioselective C(sp3)?C(CO) bond-cleavage step, provided heavily functionalized β-ketophosphonates. This novel method based on a readily available reaction system exhibits wide scope, high functional-group tolerance, and exclusive selectivity.
[2 + 2] cycloaddition of cyclic vinyl phosphonates with ketenes
Ruder, Suzanne M.,Ding, Min
, p. 1771 - 1776 (2007/10/03)
Highly substituted cyclic β-alkoxyvinyl phosphonates underwent thermal [2+2] cycloaddition with activated ketenes to afford bicyclic phosphonates. Fragmentation of the central polarized bond of this bicyclic system occurred readily upon treatment with zin
PHOSPHORYLATION OF 1-MORPHOLINOCYCLOHEXENE AND CYCLOPENTENE. CONVENIENT METHOD OF SYNTHESIS OF α-PHOSPHORYLATED DERIVATIVES OF CYCLOHEXANONE AND CYCLOPENTANONE
Tolmachev, A. A.,Kostyuk, A. N.,Morozova, L. N.,Lampeka, R. D.,Kozlov, E. S.,Pinchuk, A. M.
, p. 1475 - 1484 (2007/10/02)
It was shown that 1-morpholinocyclopentene and 1-morpholinocyclohexene are readily phosphorylated by phosphorus(III) halides in the presence of triethylamine.From the compounds obtained, α-phosphorylated cyclopentanones and cyclohexanones were synthesized