1080-67-7

Basic information

• Product Name: [4S,4aβ,8aα,(-)]-Decahydro-1,6-bis(methylene)-4-isopropylnaphthalene
• Synonyms: (-)-4(14),10(15)-Cadinadiene;[4S,4aβ,8aα,(-)]-Decahydro-1,6-bis(methylene)-4-isopropylnaphthalene
• CAS NO: 1080-67-7
• Molecular Formula: C15H24
• Molecular Weight: 204.35106
• Mol File: 1080-67-7.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: [4S,4aβ,8aα,(-)]-Decahydro-1,6-bis(methylene)-4-isopropylnaphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: [4S,4aβ,8aα,(-)]-Decahydro-1,6-bis(methylene)-4-isopropylnaphthalene(1080-67-7)
• EPA Substance Registry System: [4S,4aβ,8aα,(-)]-Decahydro-1,6-bis(methylene)-4-isopropylnaphthalene(1080-67-7)

Safety Data

• Hazardous Substances Data: 1080-67-7(Hazardous Substances Data)

Usage

General Description

Decahydro-1,6-bis(methylene)-4-isopropylnaphthalene is a chemical compound with the molecular formula C15H26. It is a bicyclic terpene derivative with a unique structure that includes two fused cyclohexane rings and a methyl group attached to one of the rings. [4S,4aβ,8aα,(-)]-Decahydro-1,6-bis(methylene)-4-isopropylnaphthalene has potential uses in the fragrance and flavor industry due to its aromatic properties. Additionally, it may have applications as a chemical intermediate in the synthesis of other organic compounds. The unique structure and properties of Decahydro-1,6-bis(methylene)-4-isopropylnaphthalene make it an interesting target for further research and potential applications in various industries.

Upstream product

• 106777-60-0 (1R*,5S*,6R*,8S*)-(+/-)-8-Hydroxy-5-isopropylbicyclo<4.4.0>decan-2-on 
• 106777-60-0 (1R*,5S*,6R*,8R*)-(+/-)-8-Hydroxy-5-isopropylbicyclo<4.4.0>decan-2-on 
• 106777-64-4 (1R*,5S*,6R*,8S*)-(+/-)-5-Isopropyl-2-methylenbicyclo<4.4.0>decan-8-ol 
• 106777-59-7 2,8-Diacetoxy-5-isopropylbicyclo<4.4.0>dec-1-en 
• 106777-57-5 N,N-Diethyl<6-(3-butenyl)-4-isopropyl-1,4-cyclohexadienyl>oxyethylamin 
• 106777-58-6 2-(3-Butenyl)-4-isopropyl-2-cyclohexen-1-on 
• 80873-83-2 1-(2-Diethylaminoethoxy)-4-isopropyl-cyclohexadien-1,4 
• 105453-16-5 germacrene D 
• 1080-68-8 (1R*,5S*,6R*)-(+/-)-5-Isopropylbicyclo<4.4.0>decan-2,8-dion 
• 19493-09-5 Methylenetriphenylphosphorane 
• 27548-51-2 (1R*,5S*,6R*)-(+/-)-5-Isopropyl-2-methylenbicyclo<4.4.0>decan-8-on 
• 29292-27-1 (5R*,6R*)-(+/-)-5-Isopropyl-8-methoxybicyclo<4.4.0>dec-8-en-2-on 
• 2158-59-0 cryptone 
• 27548-51-2 (1R*,5R*,6R*)-(+/-)-5-Isopropyl-8-methylenbicyclo<4.4.0>decan-8-on 

Downstream Products

• 483-73-8 cis-cadin-4-en-7-ol 

Relevant articles and documents

The role of germacrene D as a precursor in sesquiterpene biosynthesis: Investigations of acid catalyzed, photochemically and thermally induced rearrangements

Germacrene D is considered as a precursor of many sesquiterpene hydrocarbons. We have investigated the acid catalyzed as well as the photochemically and thermally induced rearrangement processes of germacrene D isolated from several Solidago species, which contain both enantiomers of germacrene D. Enantiomeric mixtures of sesquiterpenes of the cadinane, eudesmane (selinane), oppositane, axane, isodaucane, and bourbonane group as well as isogermacrene D were identified as main products and made available as reference compounds for structure investigations and stereochemical assignments of plant constituents. δ-Amorphene, one of the rearrangement products, was identified as a natural product for the first time. The absolute configuration of γ-amorphene was revised by correlation with the absolute configuration of germacrene D. The mechanisms of the rearrangement reactions are discussed. (C) 2000 Elsevier Science Ltd.

Asymmetric Intramolecular Ene Reaction Catalyzed by a Chiral Titanium Reagent and Synthesis of (-)-ε-Cadinene

A highly diastereo- and enantio-selective intramolecular ene reaction was developed by employing a chiral titanium reagent generated in situ from TiCl2(OPri)2 and a tartrate-derived chiral 1,4-diol.This reaction afforded masked cyclohexanone an

Stereoisomeric ε-Dienes of the Cadalane Series: Synthesis and Configurational Correlation

rac-ε-Cadinene (1) and rac-ε-amorphene (4) were prepared by Wittig reaction of the diketones 9 and 10, obtained by ?-cyclization (7->8), and alternatively from the keto alcohols 11b and 12b. rac-ε-bulgarene (3) was prepared from the ene-ol 15b, available from 11b by Wittig reaction via epimerization.The ketones 10 and 12b are not epimerizable, so rac-ε-muurolene (2) was obtained from the enone 24, accessible by Diels-Alder reaction (21 + 22 ->23). - Configurational assignments of 1 - 4 and of the bicyclic precursors are confirmed by the 13C-NMR spectra supported by 2D-INADEQUATE experiments.