108037-18-9

Basic information

• Product Name: ((C₅H₅)Fe)2(C₅H₄CH(P(C₆H₅)3)COC₅H₄)⁽¹⁺⁾*I^(1-)=[((C₅H₅)Fe)2(C₅H₄CH(P(C₆H₅)3)COC₅H₄)]I
• CAS NO: 108037-18-9
• Molecular Weight: 800.282
• Mol File: 108037-18-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((C₅H₅)Fe)2(C₅H₄CH(P(C₆H₅)3)COC₅H₄)⁽¹⁺⁾*I^(1-)=[((C₅H₅)Fe)2(C₅H₄CH(P(C₆H₅)3)COC₅H₄)]I(CAS DataBase Reference)
• NIST Chemistry Reference: ((C₅H₅)Fe)2(C₅H₄CH(P(C₆H₅)3)COC₅H₄)⁽¹⁺⁾*I^(1-)=[((C₅H₅)Fe)2(C₅H₄CH(P(C₆H₅)3)COC₅H₄)]I(108037-18-9)
• EPA Substance Registry System: ((C₅H₅)Fe)2(C₅H₄CH(P(C₆H₅)3)COC₅H₄)⁽¹⁺⁾*I^(1-)=[((C₅H₅)Fe)2(C₅H₄CH(P(C₆H₅)3)COC₅H₄)]I(108037-18-9)

Safety Data

• Hazardous Substances Data: 108037-18-9(Hazardous Substances Data)

Upstream product

• 1293-79-4 ferrocenoyl chloride 

Relevant articles and documents

Synthesis of ferrocenyl-1,2-diketones and related compounds: Crystal and molecular structures of 1,2-diferrocenylethanedione and 1-ferrocenyl-2-(4-biphenylyl) ethanedione

Ferrocenyl-1,2-diketones FcCOCOR, 3, [Fc = (C5H5)Fe(C5H4)] can be prepared by oxidation of acylferrocenes FcCOCH2R or, more efficiently, by oxidation of the isomeric ketones FcCH2COR, 2. The ketones 2 are in turn readily synthesized from the salt (FcCH2PPh3)+I- via the acylated salts [FcCH(COR)PPh3]+I-. The haloacylferocenes FcCOCClxH3-x (x = 1, 2, 3, of which the x = 2 example is synthetically equivalent to a diketone) are synthesized by Friedel-Crafts acylation of ferrocene using CClxH3-xCOCl/AlCl3, but the reaction proceeds via two parallel pathways, one giving the normal acyl derivatives FcCOCClxH3-x and the other giving the reduced products FcCOCClx-1H4-x. Two diketones FcCOCOFc 3b and FcCOCOC6H4Ph 3c have been structurally characterised by single-crystal X-ray diffraction.