1082438-44-5Relevant articles and documents
Nonplanar structures of thioamides derived from 7-azabicyclo[2.2.1]heptane. Electronically tunable planarity of thioamides
Hori, Tetsuharu,Otani, Yuko,Kawahata, Masatoshi,Yamaguchi, Kentaro,Ohwada, Tomohiko
, p. 9102 - 9108 (2008)
X-ray crystallographic analysis showed that N-thiobenzoyl-7-azabicyclo[2.2. 1]heptane displays marked nonplanarity of the thioamide (1a, α = 167.1° and |τ| = 11.2°) as compared with the corresponding monocyclic pyrrolidine thioamide (2a, α = 174.7° and |τ