1085-62-7

Basic information

• Product Name: (1,4,5,6,7,7-hexachlorobicyclo[2.2.1]hept-5-en-2-yl)methyl acetate
• CAS NO: 1085-62-7
• Molecular Formula: C₁₀H₈Cl₆O₂
• Molecular Weight: 372.8873
• Mol File: 1085-62-7.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 372.4°C at 760 mmHg
• Flash Point: 142.2°C
• Density: 1.66g/cm³
• Vapor Pressure: 9.67E-06mmHg at 25°C
• Refractive Index: 1.581
• CAS DataBase Reference: (1,4,5,6,7,7-hexachlorobicyclo[2.2.1]hept-5-en-2-yl)methyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (1,4,5,6,7,7-hexachlorobicyclo[2.2.1]hept-5-en-2-yl)methyl acetate(1085-62-7)
• EPA Substance Registry System: (1,4,5,6,7,7-hexachlorobicyclo[2.2.1]hept-5-en-2-yl)methyl acetate(1085-62-7)

Safety Data

• Hazardous Substances Data: 1085-62-7(Hazardous Substances Data)

Usage

General Description

(1,4,5,6,7,7-hexachlorobicyclo[2.2.1]hept-5-en-2-yl)methyl acetate is a synthetic chemical compound with a complex molecular structure. It is a derivative of the naturally occurring compound, bicyclic monoterpenoid, and belongs to the class of chlorinated compounds. This chemical has been developed for use in insecticides and pesticides due to its strong insecticidal properties. However, it is also known to be highly toxic to humans and the environment, and its use is regulated and restricted in many countries. The chemical is considered to be a persistent organic pollutant due to its long-term persistence in the environment and its potential to bioaccumulate in the food chain. As a result, there is ongoing research and regulatory efforts to assess and minimize the risks associated with this chemical.

Upstream product

• 1080-25-7 5-hydroxymethyl-1,2,3,4,7,7-hexachlorobicyclo<2.2.1>hept-2-ene 
• 64-19-7 acetic acid 
• 77-47-4 hexachlorocyclopentadiene 
• 1080-25-7 rac-((1R,2S,4S)-1,4,5,6,7,7-hexachlorobicyclo[2.2.1]hept-5-en-2-yl)methanol 
• 75-36-5 acetyl chloride 
• 591-87-7 Allyl acetate 
• 108-24-7 acetic anhydride 

Downstream Products

• 95-12-5 (-)-(1S,2S,4S)-bicyclo[2.2.1]hept-5-en-2-yl methanol 

Relevant articles and documents

Enzymatic resolution of (±)-2-endo-hydroxymethyl and acetoxymethyl substituted hexachloronorbornene derivatives

(±)-2-endo-Hydroxymethyl-1,4,5,6,7,7-hexachlorobicyclo[2.2.1] hept-5-ene and (±)-2-endo-acetoxymethyl-1,4,5,6,7,7-hexachlorobicyclo[2. 2.1]hept-5-ene were resolved by using various hydrolases to afford enantiomerically enriched products with ees of 94-98%. The absolute configuration was determined by transforming 2-endo-acetoxymethyl-1,4,5,6,7,7- hexachlorobicyclo[2.2.1]hept-5-ene into 2-endo-hydroxymethyl-bicyclo[2.2.1]hept- 5-ene with known absolute configuration.

DIENOPHILIC ACTIVITY OF ALLYL HALOGENOACETATES IN REACTION WITH HEXACHLOROCYCLOPENTADIENE

The kinetics of the diene condensation of hexachlorocyclopentadiene with allyl monochloroacetate, monobromoacetate, and acetate were investigated by GLC.The kinetic and thermodynamic parameters of the reactions were determined.By a comparative analysis of the results it was shown that the nature of the electronwithdrawing substituent affects the dienophilic activity of the allyl esters in diene condensation with hexachlorocyclopentadiene.