108530-14-9

Basic information

• Product Name: 1,1,1-trifluoro-N-phenylmethanesulfinamide
• Synonyms: 1,1,1-trifluoro-N-phenylmethanesulfinamide
• CAS NO: 108530-14-9
• Molecular Weight: 209.192
• Mol File: 108530-14-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,1,1-trifluoro-N-phenylmethanesulfinamide(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,1-trifluoro-N-phenylmethanesulfinamide(108530-14-9)
• EPA Substance Registry System: 1,1,1-trifluoro-N-phenylmethanesulfinamide(108530-14-9)

Safety Data

• Hazardous Substances Data: 108530-14-9(Hazardous Substances Data)

Upstream product

• 421-83-0 trifluoromethane sulfonyl chloride 
• 62-53-3 aniline 
• 81290-20-2 (trifluoromethyl)trimethylsilane 
• 222851-56-1 N-phenylsulfinylamine 
• 2926-29-6 Langlois reagent 

Relevant articles and documents

Intermolecular C-N addition of amides and S-N addition of sulfinamides to arynes

An efficient, mild, transition-metal-free method has been developed for the intermolecular C-N σ-bond addition of amides and S-N σ-bond addition of sulfinamides to arynes to form one C-C bond and one heteroatom-carbon bond in one step at room temperature. Evidence for a stepwise mechanism is provided. Copyright

A new equivalent of the CF3S(O)+ cation. Synthesis of trifluoromethanesulfinates and trifluoromethanesulfinamides

The solution of sodium trifluoromethanesulfinate (sodium 'triflinate' and phosphoryl chloride (2/1), in AcOEt, behaves like an equivalent of the CF3S(O)+ cation. It can be used in situ to prepare trifluoromethanesulfinates (CF3S(O)OR) or trifluoromethanesulfinamides (CF3S(O)NHR) at room temperature from alcohols or amines, respectively.