109469-92-3

Basic information

• Product Name: 3-nitro-6-phenylphenanthridine
• Synonyms: 3-nitro-6-phenylphenanthridine
• CAS NO: 109469-92-3
• Molecular Weight: 300.316
• Mol File: 109469-92-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-nitro-6-phenylphenanthridine(CAS DataBase Reference)
• NIST Chemistry Reference: 3-nitro-6-phenylphenanthridine(109469-92-3)
• EPA Substance Registry System: 3-nitro-6-phenylphenanthridine(109469-92-3)

Safety Data

• Hazardous Substances Data: 109469-92-3(Hazardous Substances Data)

Upstream product

• 5570-18-3 2-aminophenylboronic acid 
• 183110-88-5 2-bromo-5-nitro-benzophenone 
• 159624-15-4 tert-butyl N-[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]carbamate 
• 3292-42-0 2-aminobenzenethiol hydrochloride 
• 34052-37-4 2-chloro-5-nitrobenzophenone 
• 98-88-4 benzoyl chloride 
• 6272-52-2 2-(4-nitrophenyl)aniline 
• 98-07-7 Benzotrichlorid 
• 412337-65-6 N-(4'-nitro-biphenyl-2-yl)-benzamide 
• 111326-35-3 2-nitro-11-phenyl-dibenzo[b,f][1,4]thiazepine 

Downstream Products

• 62394-26-7 6-phenyl-phenanthridin-8-ylamine 

Relevant articles and documents

Assembly of substituted phenanthridines via a cascade palladium-catalyzed coupling reaction, deprotection and intramolecular cyclization

The discovery and development of a general method for the one-pot synthesis of substituted phenanthridines is presented. In the presence of Pd(PPh3)4, accessible precursors undergo a Suzuki cross-coupling reaction with 2-(Boc-amino)benzeneboronic acid pinacol ester and then spontaneously undergo deprotection and intramolecular condensation to form the corresponding phenanthridines in one step. This reaction has a wide range of substrates with various functional groups, and the corresponding products have been obtained in good yields.