109548-52-9

Basic information

• Product Name: phenyl 1-thiocyanoethylcarbonate
• Synonyms: phenyl 1-thiocyanoethylcarbonate
• CAS NO: 109548-52-9
• Molecular Weight: 223.252
• Mol File: 109548-52-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: phenyl 1-thiocyanoethylcarbonate(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl 1-thiocyanoethylcarbonate(109548-52-9)
• EPA Substance Registry System: phenyl 1-thiocyanoethylcarbonate(109548-52-9)

Safety Data

• Hazardous Substances Data: 109548-52-9(Hazardous Substances Data)

Upstream product

• 50972-20-8 phenyl-α-chloroethyl-carbonate 
• 1147550-11-5 ammonium thiocyanate 

Downstream Products

• 108-95-2 phenol 
• 117972-13-1 phenyl 1-isothiocyanoethylcarbonate 

Relevant articles and documents

SYNTHESIS OF THIOCYANATE AND ISOTHIOCYANATE SUBSTITUTED CARBONATES AND CARBAMATES

Reactions of alkyl 1-chloroethyl carbonates 1 and 1-chloroethyl N,N-dialkyl carbamates 2 with MSCN (M=K, NH4) in acetone or in protic solvents (MeOH, HCONH2) afforded the corresponding thio- and/or isothiocyano derivates in good yields.The origin of the N-bonded compounds is discussed and it is concluded that most of these compounds must be due to a N condensation of the thiocyanate anion.During this work, we also found a new very mild method for isomerizing in good yields alkyl 1-thiocyanoethyl carbonates and 1-thiocyanoethyl N,N-dialkyl carbamates to their corresponding isothiocyano derivates.