1097634-92-8Relevant articles and documents
Synthesis of 1-hydroperoxy-1′-alkoxyperoxides by the iodine-catalyzed reactions of geminal bishydroperoxides with acetals or enol ethers
Terent'ev, Alexander O.,Platonov, Maxim M.,Krylov, Igor B.,Chernyshev, Vladimir V.,Nikishin, Gennady I.
experimental part, p. 4435 - 4441 (2009/02/08)
It was found that iodine-catalyzed reactions of geminal bishydroperoxides with acetals proceed with the replacement of only one alkoxy group by the peroxide group to give previously unknown structures of 1-hydroperoxy-1′- alkoxyperoxides in yields up to 64%. The same compounds are formed in the iodine-catalyzed reactions of geminal bishydroperoxides with enol ethers. The nature of the solvent has a decisive influence on the formation of 1-hydroperoxy-1′-alkoxyperoxides. In the series of Et2O, THF, EtOH, CHCl3, CH3CN, and hexane, the best results were obtained with the use of Et2O or THF as the solvent.
