110055-34-0

Basic information

• Product Name: bis(3,4-dimethoxybenzyl) sulfide
• Synonyms: bis(3,4-dimethoxybenzyl) sulfide
• CAS NO: 110055-34-0
• Molecular Weight: 334.436
• Mol File: 110055-34-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis(3,4-dimethoxybenzyl) sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: bis(3,4-dimethoxybenzyl) sulfide(110055-34-0)
• EPA Substance Registry System: bis(3,4-dimethoxybenzyl) sulfide(110055-34-0)

Safety Data

• Hazardous Substances Data: 110055-34-0(Hazardous Substances Data)

Upstream product

• 21852-32-4 4-bromomethyl-1,2-dimethoxybenzene 
• 7306-46-9 4-chloromethyl-1,2-dimethoxy-benzene 
• 93-03-8 (3,4-dimethoxyphenyl)methanol 

Downstream Products

• 215384-53-5 bis(3,4-dimethoxybenzyl) sulfoxide 

Relevant articles and documents

Oxidative biaryl coupling reaction of phenol ether derivatives using a hypervalent lodine(III) reagent

The hypervalent iodine(III)-induced intramolecular biaryl coupling reaction of phenol ether derivatives (nonphenolic derivatives) was investigated with the aim of preparing various dibenzo heterocyclic compounds. 1,3-Diarylpropanes (la-e), AT-benzyl-W-phenethylamines (2a-c) and N,Ndibenzylamines (3a-e) react with a hypervalent iodine reagent, phenyliodine(III) bis(trifluoroacetate) (PIFA), containing BF3·Et2O in CH2Cl2 to give the biaryl coupling products (4-6) in good yield. As an application of the reaction, we examined the synthesis of oxygen- and sulfur-containing dibenzoheterocyclic compounds (12-15), whose side chain moiety could be easily cleaved by the known method to give 2,2'-substituted biphenyl compounds (16-18).