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110235-47-7

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110235-47-7 Usage

Uses

Different sources of media describe the Uses of 110235-47-7 differently. You can refer to the following data:
1. Mepanipyrim is an anilinopyrimidine fungicide which have been used in the management of fungal diseases in strawberries.
2. Agricultural fungicide.
3. Mepanipyrim is a non-systemic fungicide that provides preventative control of diseases in pome fruits (scab), vines, strawberries, tomatoes and cucumbers (grey mould) and peaches (brown rots) caused by Botrytis cinerea, Venturia inaequaris and Monilinia fructicola.

Definition

ChEBI: A member of the class of aminopyrimidines that is N-phenylpyrimidin-2-amine carrying additional methyl and 1-propynyl substituents at positions 4 and 6 respectively. A fungicide used to control a wide range of diseases including grey mou d on strawberries, tomatoes and cucumabers, and scab on apples and pears.

Metabolic pathway

By tomato seedlings, 14C-mepanipyrim is biotransformed via the pathways including elimination of the phenyl group, hydroxylation of the propynyl moiety, and hydroxylation at the phenyl ring to yield several kinds of metabolite, and 2- and 4-[4-methyl-6- (1-propynyl)pyrimidin-2-ylamino]phenols, 1-(2-anilino-6- methylpyrimidin-4-yl)-2-propanol, and 4-methyl-6-(1- propynyl)pyrimidin-2-ylamine are tentatively identified as major metabolites. In soils under laboratory conditions, 14C-mepanipyrim undergoes degradation to give the degradation products and the main pathway is elimination of the phenyl group.

Degradation

Mepanipyrim (1) is stable to hydrolytic degradation in the pH range 4-9 with a DT50 >1 year. It decomposed rapidly in water when exposed to light (DT50 13 days) (PM).

Check Digit Verification of cas no

The CAS Registry Mumber 110235-47-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,0,2,3 and 5 respectively; the second part has 2 digits, 4 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 110235-47:
(8*1)+(7*1)+(6*0)+(5*2)+(4*3)+(3*5)+(2*4)+(1*7)=67
67 % 10 = 7
So 110235-47-7 is a valid CAS Registry Number.
InChI:InChI=1/C14H13N3/c1-3-7-13-10-11(2)15-14(17-13)16-12-8-5-4-6-9-12/h4-6,8-10H,1-2H3,(H,15,16,17)

110235-47-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name mepanipyrim

1.2 Other means of identification

Product number -
Other names 4-methyl-N-phenyl-6-(1-propynyl)-2-pyrimidinamine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:110235-47-7 SDS

110235-47-7Downstream Products

110235-47-7Related news

Effectiveness of different advanced oxidation processes (AOPs) on the abatement of the model compound MEPANIPYRIM (cas 110235-47-7) in water08/10/2019

This study aims to present the effectiveness of different advanced oxidation processes (AOPs) as photolysis (UV mercury arc and Xe-arc), ozone, ozone/Hg-UV, and photocatalysis (suspended and immobilized TiO2) for the degradation of the fungicide mepanipyrim in aqueous solutions. A well-known com...detailed

Modelling the isothermal degradation kinetics of metrafenone and MEPANIPYRIM (cas 110235-47-7) in a grape juice analog08/09/2019

Five photodegradation products of metrafenone (MTF) and six of mepanipyrim (MEP) were identified in synthetic grape juice at 25 °C and the structures of the main reaction products established. The degradation of MTF and MEP was modelled by using three different strategies involving monitoring (...detailed

Impact of fungicides MEPANIPYRIM (cas 110235-47-7) and tetraconazole on phenolic profile and colour of Mencía red wines08/08/2019

The influence of mepanipyrim (Mep) and tetraconazole (Tetra) and their formulations (Mep-Form and Tetra-Form) on the chromatic characteristics of Mencía wines was evaluated. Fungicides were applied at concentrations corresponding to their Maximum Residue Levels (MRL) on grapes and at 2MRL. The ...detailed

110235-47-7Relevant articles and documents

Method for preparing mepanipyrim

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, (2018/07/30)

The invention provides a preparation method of mepanipyrim and belongs to the field of pesticide chemical synthesis technologies. The preparation method of the mepanipyrim comprises the following steps: firstly, reacting phenyl guanidine salt with ethyl acetoacetate so as to prepare phenylamino pyrimidone, reacting the phenylamino pyrimidone with phosphorus oxychloride so as to prepare 2-chloro-pyrimidine phenylamine; subsequently, carrying out coupling and crossing reaction between the 2-chloro-pyrimidine phenylamine and alkyne so as to prepare mepanipyrim. The preparation method of mepanipyrim has the advantages that the used raw materials and reagents are cheap and easily available; the reaction process is simple, the reaction conditions are mild, the cost is low, the yield is high, a good condition is created for industrial large-scale production and commercialization of the products.

Arylphenyl-substituted cyclic keto enols

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, (2008/06/13)

The present invention relates to novel arylphenyl-substituted cyclic ketoenols, their preparation and the use of such ketoenols as pesticides and/or herbicides. The novel arylphenyl-substituted cyclic ketoenols are of the formula (I) in which CKE refers to the cyclic ketoenol and W, X, Y and Z are as defined in the specification.

Anilinopyrimidine derivatives

-

, (2008/06/13)

Anilinopyrimidine derivatives of the formula: STR1 wherein R is --CH2 C(O)CH3 or --CH=C(Cl)CH3, are useful as intermediates in the production of anilinopyrimidine fungicides.

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