110522-70-8

Basic information

• Product Name: 3,4-di-O-allyl-2,5-di-O-benzyl-L-ido-hexodialdose
• Synonyms: 3,4-di-O-allyl-2,5-di-O-benzyl-L-ido-hexodialdose
• CAS NO: 110522-70-8
• Molecular Weight: 438.521
• Mol File: 110522-70-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3,4-di-O-allyl-2,5-di-O-benzyl-L-ido-hexodialdose(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4-di-O-allyl-2,5-di-O-benzyl-L-ido-hexodialdose(110522-70-8)
• EPA Substance Registry System: 3,4-di-O-allyl-2,5-di-O-benzyl-L-ido-hexodialdose(110522-70-8)

Safety Data

• Hazardous Substances Data: 110522-70-8(Hazardous Substances Data)

Upstream product

• 110522-69-5 (2S,3R,4R,5S)-3,4-Bis-allyloxy-2,5-bis-benzyloxy-hexane-1,6-diol 
• 110550-25-9 3,4-di-O-allyl-2,5-di-O-benzyl-D-chiro-inositol 
• 100-39-0 benzyl bromide 
• 40617-60-5 1,2:5,6-bis-O-(1-methylethylidene)-D-chiro-inositol 
• 700863-94-1 3,4-di-O-allyl-D-chiro-inositol 
• 701272-07-3 3,4-di-O-allyl-1,2:5,6-di-O-isopropylidene-D-chiro-inositol 
• 487-44-5 D-(+)-glucuronic acid γ-lactone 
• 100-44-7 benzyl chloride 
• 114343-02-1 (2S,3S,3aR,5S,6R,6aR)-2,5-Dimethoxy-hexahydro-furo[3,2-b]furan-3,6-diol 
• 114343-01-0 (3aR,3bS,5S,6S,6aR,7aR)-5-Methoxy-2,2-dimethyl-hexahydro-furo[2',3':4,5]furo[2,3-d][1,3]dioxol-6-ol 
• 94926-00-8 2,5-di-O-benzyl-L-iditol 
• 110522-64-0 (2S,3S,3aS,5S,6R,6aS)-3,6-Bis-benzyloxy-2,5-dimethoxy-hexahydro-furo[3,2-b]furan 
• 30694-75-8 Toluene-4-sulfonic acid (3aR,3bS,6R,6aS,7aR)-5-hydroxy-2,2-dimethyl-hexahydro-furo[2',3':4,5]furo[2,3-d][1,3]dioxol-6-yl ester 
• 110522-66-2 (2S,3S,4S,5S)-2,5-Bis-benzyloxy-1,6-bis-trityloxy-hexane-3,4-diol 

Downstream Products

• 700863-98-5 N-benzyl-3,6-di-O-benzyl-L-ido-3,4,5,6-tetrahydroxyazepane 
• 700863-97-4 4,5-di-O-allyl-N-benzyl-3,6-di-O-benzyl-L-ido-3,4,5,6-tetrahydroxyazepane 
• 104873-73-6 1L-5,6-di-O-allyl-1,4-di-O-benzyl-myo-inositol 
• 110611-87-5 (1R,2R,3S,4R,5R,6S)-4,5-Bis-allyloxy-3,6-bis-benzyloxy-cyclohexane-1,2-diol 
• 110550-25-9 3,4-di-O-allyl-2,5-di-O-benzyl-D-chiro-inositol 

Relevant articles and documents

Conformation inversion of an inositol derivative by use of silyl ethers: A modified route to 3,6-di-O-substituted-L-ido-tetrahydroxyazepane derivatives

The tans-diequatorial 3,4-diol of 2,5-di-O-benzyl-D-chiro-inositol cleaved selectively with the periodate ion in the presence of the trans-diaxial 1,6-diol to give a dialdehyde (dialdose) from which 3,6-di-O-benzyl-D- mannotetrahydroxyazepane (1) was made. The trans-diaxial 1,6-diol of 3,4-di-O-allyl-2,5-di-O-benzyl-D-chiro-inositol was not cleaved satisfactorily by periodate, but replacement of the allyl substituents with tert-butyldimethylsilyl groups caused conformational inversion of the inositol ring, and the resulting trans-diequatorial 1,6-diol cleaved efficiently to give a dialdehyde from which 3,6-di-O-benzyl-L-tdo-tetrahydroxyazepane (2) can be prepared.