110598-48-6Relevant articles and documents
The efficient stereoselective synthesis of Z-vinylsilanes through the Suzuki-Miyaura coupling of Z-(α-silylvinyl)borinates
Soderquist, John A.,Leon, Gisela
, p. 3989 - 3990 (2007/10/03)
Air-stable Z-(α-silylvinyl)borinates (2), easily prepared in a hydroboration-oxidation sequence from I provide a particularly effective route to Z-vinylsilanes (3, 59-97%) through Suzuki-Miyaura coupling.
PALLADIUM-CATALYSED REDUCTIVE ADDITION OF ARYL IODIDES TO ARYL AND ALKYLETHYNYLSILANES: A STEREO AND REGIOSELECTIVE ROUTE TO FUNCTIONALIZED 2,2-DISUBSTITUTED VINYLSILANES
Arcadi, A.,Cacchi, S.,Marinelli, F.
, p. 6397 - 6400 (2007/10/02)
Aryl and alkylethynylsilanes are converted into 2,2-disubstituted vinylsilanes containing various common functional groups in the presence of aryl iodides, a palladium catalyst, formic acid, and a tertiary or secondary amine with high stereoselectivity an