111113-91-8

Basic information

• Product Name: 8-Benzyliden-5,6,7,8-tetrahydrochinolinium-1-(ethoxycarbonylaminid)
• CAS NO: 111113-91-8
• Molecular Weight: 308.38
• Mol File: 111113-91-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 8-Benzyliden-5,6,7,8-tetrahydrochinolinium-1-(ethoxycarbonylaminid)(CAS DataBase Reference)
• NIST Chemistry Reference: 8-Benzyliden-5,6,7,8-tetrahydrochinolinium-1-(ethoxycarbonylaminid)(111113-91-8)
• EPA Substance Registry System: 8-Benzyliden-5,6,7,8-tetrahydrochinolinium-1-(ethoxycarbonylaminid)(111113-91-8)

Safety Data

• Hazardous Substances Data: 111113-91-8(Hazardous Substances Data)

Upstream product

• 28707-60-0 8-benzylidene-5,6,7,8-tetrahydroquinoline 
• 541-41-3 chloroformic acid ethyl ester 
• 111113-96-3 1-Amino-8-benzyliden-5,6,7,8-tetrahydrochinolinium-mesitylensulfonat 

Downstream Products

• 28707-60-0 8-benzylidene-5,6,7,8-tetrahydroquinoline 
• 111114-00-2 9,10-Dihydro-1-phenyl-3H,8H-pyrimido<5,6,1-i,j>chinolin-3-on 

Relevant articles and documents

A Light-Induced Unusual Synthesis of Substituted 3-Azaquinolizinones

We describe the photochemical transformations of the cycloalkane-annulated pyridinium-N-aminides 8-10, which are conjugated with a benzylidene system.With 8, 1,3-electrocyclisation takes place leading to the cyclopenta-1,2-diazepine 25 via the diazanorcaradiene 12 which subsequently underwent valence tautomerisation.Contrary to 8, with 9 and 10, 1,5-electrocyclisation is dominating yielding 14 and 15 as nonisolable intermediates; these rearrange in a rationalized reaction sequence e.g. 29 -> 30a 30b -> 26 to give the novel 3-azaquinolizinones 26 and 27, respectively.The structure of 27 is proven by X-ray diffraction.