111613-37-7

Basic information

• Product Name: 1-((1R,3S,6R)-6-methyl-7-oxabicyclo[4.1.0]heptan-3-yl) ethanone
• Synonyms: 1-((1R,3S,6R)-6-methyl-7-oxabicyclo[4.1.0]heptan-3-yl) ethanone;1-[(1S,3S,6R)-6-methyl-7-oxabicyclo[4.1.0]hept-3-yl]Ethanone
• CAS NO: 111613-37-7
• Molecular Formula: C₉H₁₄O₂
• Molecular Weight: 154.20626
• Mol File: 111613-37-7.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 220.1±23.0 °C(Predicted)
• Appearance: /
• Density: 1.084±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 1-((1R,3S,6R)-6-methyl-7-oxabicyclo[4.1.0]heptan-3-yl) ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-((1R,3S,6R)-6-methyl-7-oxabicyclo[4.1.0]heptan-3-yl) ethanone(111613-37-7)
• EPA Substance Registry System: 1-((1R,3S,6R)-6-methyl-7-oxabicyclo[4.1.0]heptan-3-yl) ethanone(111613-37-7)

Safety Data

• Hazardous Substances Data: 111613-37-7(Hazardous Substances Data)

Usage

General Description

1-((1R,3S,6R)-6-methyl-7-oxabicyclo[4.1.0]heptan-3-yl) ethanone is a chemical compound with a complex, bicyclic structure. It is composed of an ethanone (ketone) group attached to a seven-membered ring system with a methyl group and oxygen atom. The compound's stereochemistry is specified as 1R, 3S, and 6R, indicating the positions of the substituents on the ring. This chemical may have potential applications in organic synthesis, pharmaceuticals, or material science due to its unique structure and reactivity. Further research and testing of this compound are necessary to fully understand its properties and potential uses.

Upstream product

• 203719-53-3 (-)-limonene oxide 
• 5989-54-8 (-)-(S)-limonene 
• 124-40-3 dimethyl amine 

Downstream Products

• 111613-41-3 (Z)-(1R,2S,4S)-4-(1',5'-Dimethylhexa-1',4'-dienyl)-1,2-epoxy-1-methylcyclohexane 
• 214333-53-6 erythro-(1R,2S,4S)-4-(1',5'-Dimethyl-2'-diphenylphosphinoyl-1'-hydroxyhex-4'-enyl)-1,2-epoxy-1-methylcyclohexane 

Relevant articles and documents

Highly stereoselective syntheses of the sex pheromone components of the southern green stink bug Nezara viridula (L.) and the green stink bug Acrosternum hilare (say)

Diastereoisomeric (Z)-(1R,2S,4S)- and (Z)-(1S,2R,4S)-epoxybisabolenes (1 and 2), sex pheromone components of the stink bugs Nezara viridula and Acrosternum hilare were synthesized stereoselectively in three steps from commercially available (-)-limonene oxide 3. Two other stereoisomers, (E)- (1R,2S,4S)- and (E)-(1S,2R,4S)-epoxybisabolenes (7 and 9) were obtained in two steps from the same starting material. The other four stereoisomers are also accessible by simply substituting (+)-limonene oxide for 3, providing short, stereoselective routes to all eight possible stereoisomers.

Biosynthesis of verrucarin and roridin derivatives. V. Synthesis of two pairs of diastereoisomers of (1,8 C14) α bisabolol and attempts to incorporate these in verrucarol

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