1121-33-1Relevant articles and documents
Regioselective synthesis of 2,2-dimethylcyclopentanone using 2-pyrrolidone magnesium salt as electrogenerated base
Bonafoux, Dominique,Bordeau, Michel,Biran, Claude,Dunogues, Jacques
, p. 93 - 98 (2007/10/03)
An efficient, direct and regioselective preparation of 2,2-dimethylcyclopentanone, via its enolate precursor regioselectively obtained using the 2-pyrrolidone magnesium salt, a base electrogenerated in DME/HMPA, is reported.
Chemo- and Stereo-selective Preparation of Cyclopentanone Derivatives from Cyclohexenones using Trimethylstannyl-lithium as a Key Reagent
Sato, Tadashi,Watanabe, Toshiyuki,Hayata, Toshihiro,Tsukui, Tohru
, p. 153 - 154 (2007/10/02)
Upon treatment with trimethylsilyl trifluoromethane-sulphonate, β-stannylcyclohexanones afforded cyclopentanones chemo- and stereo-selectively.
CUPRATE ADDITIONS TO 5-METHOXYCYCLOPENTENONES: A NOVEL STEREOELECTRONIC EFFECT
Smith III, Amos B.,Dunlap, Norma K.,Sulikowski, Gary A.
, p. 439 - 442 (2007/10/02)
Cuprate additions to 5-methoxy-2-cyclopentenone have been found to proceed with moderate to extremely high diastereofacial selectivity, depending upon the specific cuprate and reaction protocol employed.Comparisons with related 5-substitued cyclopentenones suggest that the observed selectivity is not simply steric in nature, but instead reflects a novel stereoelectronic effect.