112150-34-2

Basic information

• Product Name: Phosphinous acid, dicyclohexyl-, [(2S)-1-(dicyclohexylphosphino)-2-pyrrolidinyl]methyl ester
• CAS NO: 112150-34-2
• Molecular Formula: C29H53NOP2
• Molecular Weight: 493.693
• Mol File: 112150-34-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Phosphinous acid, dicyclohexyl-, [(2S)-1-(dicyclohexylphosphino)-2-pyrrolidinyl]methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphinous acid, dicyclohexyl-, [(2S)-1-(dicyclohexylphosphino)-2-pyrrolidinyl]methyl ester(112150-34-2)
• EPA Substance Registry System: Phosphinous acid, dicyclohexyl-, [(2S)-1-(dicyclohexylphosphino)-2-pyrrolidinyl]methyl ester(112150-34-2)

Safety Data

• Hazardous Substances Data: 112150-34-2(Hazardous Substances Data)

Upstream product

• 23356-96-9 (S)-1-Pyrrolidin-2-yl-methanol 
• 16523-54-9 chlorodicyclohexylphosphane 

Relevant articles and documents

SYNTHESE D'AMINOPHOSPHINEPHOSPHINITES CHIRAUX. UTILISATION EN REDUCTION ASYMETRIQUE CATALYTIQUE

The chiral aminophosphinephosphinites ligands (AMPP) are directly synthesized from natural amino alcohols or by reduction of formyl esters of α-amino acids and PPh2Cl. Their cationic rhodium complexes have been found to be excellent catalysts for enantioselective hydrogenation of dehydroamino acids (ee ca. 86percent, yield ca. 100percent) for example.Asymmetric reduction of ketones can also be performed with the new alkyl AMPP* modified rhodium catalyst (ee 50percent).