112306-15-7

Basic information

• Product Name: Butanoic acid, 2-diazo-3-oxo-, phenyl ester
• CAS NO: 112306-15-7
• Molecular Formula: C10H8N2O3
• Molecular Weight: 204.185
• Mol File: 112306-15-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Butanoic acid, 2-diazo-3-oxo-, phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Butanoic acid, 2-diazo-3-oxo-, phenyl ester(112306-15-7)
• EPA Substance Registry System: Butanoic acid, 2-diazo-3-oxo-, phenyl ester(112306-15-7)

Safety Data

• Hazardous Substances Data: 112306-15-7(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 1694-31-1 tert-butyl acetoacetate 
• 108-95-2 phenol 
• 134973-72-1 2-diazoacetoacetic acid 
• 6864-62-6 phenyl acetoacetate 

Downstream Products

• 1637436-80-6 phenyl (S)-2-acetyl-2-hydroxy-4-phenylpent-4-enoate 
• 1637437-05-8 phenyl 2,3-dioxobutanoate 
• 1393641-70-7 (E)-phenyl 3-((tetrahydrofuran-2-yl)oxy)but-2-enoate 
• 1328882-91-2 C₁₄H₁₃NO₅ 
• 1328882-88-7 C₁₄H₁₅NO₆ 
• 219475-92-0 2-Diazo-4-(4,7-dihydro-[1,3]dioxepin-2-yl)-3-oxo-butyric acid phenyl ester 
• 219475-80-6 2-Diazo-5,5-dimethoxy-3-oxo-pentanoic acid phenyl ester 

Relevant articles and documents

Regio- and diastereoselective crotylboration of vic-tricarbonyl compounds

Crotylboration of vic-diketoamides and vic-diketo esters was achieved with high diastereoselectivity and complementary regioselectivity. Whereas (E)-crotylboration of α,β-diketoamides resulted in high yields (91-99 %) of β-crotylated products obtained as a single diastereomer (anti), Lewis acid promoted crotylboration of α,β-diketo esters yielded the α-crotylated species with the anti product as main diastereomer. (E)-Crotylboration of α,β-diketoamides resulted in high yields (91-99 %) of β-crotylated products obtained as a single diastereomer (anti). Lewis acid promoted crotylboration of α,β-diketo esters yielded the α-crotylated species with the anti product as main diastereomer. Copyright

Cyclopentene Annulations of Alkene Radical Cations with Vinyl Diazo Species Using Photocatalysis

A direct (3+2) cycloaddition between alkenes and vinyl diazo reagents using either Cr or Ru photocatalysis is described. The intermediacy of a radical cation species enables a nucleophilic interception by vinyl diazo compounds, a departure from their trad

Rhodium(II)-catalyzed decomposition of β,γ-unsaturated diazo compounds

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