112894-58-3Relevant articles and documents
SYNTHESES OF VINYLOGOUS 4H-PYRONES FROM 2,6-DIMETHYL-4H-PYRAN-4-THIONE AND ARENYL BROMOMETHYL KETONES
Ohkata, Katsuo,Imagawa, Masao,Akiba, Kin-ya
, p. 2817 - 2820 (2007/10/02)
2,6-Dimethyl-4H-pyran-4-ylideneacetophenones (5) were prepared by desulfurization of mercaptopyrilium salts (4) with diazabicycloundecene (DBU) in moderate yield.The 1H NMR spectra in CDCl3 solution of 5 show the exclusive preference for s-cis conf