1131-29-9

Basic information

• Product Name: N-t-butyl-p-benzoquinone imine N-oxide
• Synonyms: N-t-butyl-p-benzoquinone imine N-oxide
• CAS NO: 1131-29-9
• Molecular Weight: 179.219
• Mol File: 1131-29-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-t-butyl-p-benzoquinone imine N-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: N-t-butyl-p-benzoquinone imine N-oxide(1131-29-9)
• EPA Substance Registry System: N-t-butyl-p-benzoquinone imine N-oxide(1131-29-9)

Safety Data

• Hazardous Substances Data: 1131-29-9(Hazardous Substances Data)

Upstream product

• 78375-79-8 N-t-butyl-N-(p-methoxymethylphenyl)hydroxylamine 
• 23819-68-3 N-t-butyl-N-(p-formylphenyl)hydroxylamine 
• 96259-22-2 4-methoxymethylphenylmagnesium bromide 
• 1127-42-0 N-tert-butyl-N-phenylhydroxylamine 
• 78375-81-2 N-aniline 

Downstream Products

• 19617-94-8 2,5-bis(t-butylamino)-p-benzoquinone 
• 106-51-4 p-benzoquinone 
• 83933-71-5 2-(2,2,4,4-tetramethylpyrrolidin-1-yl)-p-benzoquinone 
• 25295-92-5 2,5-bis(1,1,3,3-tetramethylbutylamino)-p-benzoquinone 
• 1520-99-6 2,5-bis(butylamino)-1,4-benzoquinone 

Relevant articles and documents

Alkyl Nitrenes from N-Alkylbenzoquinone Imine N-Oxides

Alkyl nitrenes have been generated by photolysis of two N-t-alkylbenzoquinone imine N-oxides.These mainly abstract hydrogen to give the corresponding amines which are trapped by reaction with benzoquinone.Intramolecular hydrogen abstraction followed by cyclisation to give a pyrrolidine is a minor process in one case.Attempts to generate α-substituted benzyl nitrenes in this way led mainly to the production of substituted benzyl radicals by C-N bond cleavage of the N-benzylbenzoquinone imine N-oxides.