113182-45-9Relevant articles and documents
Manganese-catalyzed cross-coupling of thiols with aryl iodides
Liu, Tsung-Jui,Yi, Chih-Lun,Chan, Chien-Ching,Lee, Chin-Fa
, p. 1029 - 1034 (2013/08/25)
A manganese-catalyzed cross-coupling reaction of thiols with aryl iodides, furnishing aryl thioethers in good to excellent yields has been reported; the system shows good functional group tolerance and enables the sterically demanding aryl iodides to couple with thiols. Coming up for ArI: A manganese-catalyzed cross-coupling reaction of thiols with aryl iodides that furnishes aryl thioethers in good to excellent yields has been reported. Functional groups such as unprotected alcohols and chloro substituents are tolerated under these reaction conditions. Moreover, this catalytic system enables the sterically demanding aryl iodides to couple with thiols (see scheme; R=aryl or alkyl).