113337-51-2

Basic information

• Product Name: 2-Propenoic acid, 3-(4-bromophenyl)-2-methoxy-, methyl ester, (Z)-
• CAS NO: 113337-51-2
• Molecular Formula: C11H11BrO3
• Molecular Weight: 271.111
• Mol File: 113337-51-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3-(4-bromophenyl)-2-methoxy-, methyl ester, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3-(4-bromophenyl)-2-methoxy-, methyl ester, (Z)-(113337-51-2)
• EPA Substance Registry System: 2-Propenoic acid, 3-(4-bromophenyl)-2-methoxy-, methyl ester, (Z)-(113337-51-2)

Safety Data

• Hazardous Substances Data: 113337-51-2(Hazardous Substances Data)

Upstream product

• 7001-18-5 methyl 2-methoxyacrylate 
• 589-87-7 1,4-bromoiodobenzene 
• 17640-25-4 methyl 2,2-dichloro-2-methoxyacetate 
• 1122-91-4 4-bromo-benzaldehyde 
• 16141-79-0 diethyl (methoxy(methoxycarbonyl)methyl)phosphonate 

Relevant articles and documents

Stereoselective synthesis of methyl (Z)-α-methoxyacrylates via two-carbon homologation of aldehydes

Methyl (Z)-α-methoxyacrylates are generated in good yields by a mild, stereospecific two-carbon homologation of a wide variety of aldehydes utilizing commercial methyl 2,2-dichloro-2-methoxyacetate and CrCl2 under Barbier conditions at room tem

A NOVEL APPROACH TO α-KETO ACID DERIVATIVES VIA PALLADIUM-CATALYZED ARYLATION AND VINYLATION OF METHYL α-METHOXYACRYLATE

Methyl α-methoxyacrylate reacts stereoselectively with aryl iodides and vinyl triflates under palladium catalysis to give enol ethers of arylpyruvates and of β,γ-unsaturated α-keto esters in good to moderate yields.