113931-84-3

Basic information

• Product Name: 1-Cyclohexene-1-acetic acid, 4-(acetyloxy)-, ethyl ester
• CAS NO: 113931-84-3
• Molecular Formula: C12H18O4
• Molecular Weight: 226.273
• Mol File: 113931-84-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Cyclohexene-1-acetic acid, 4-(acetyloxy)-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Cyclohexene-1-acetic acid, 4-(acetyloxy)-, ethyl ester(113931-84-3)
• EPA Substance Registry System: 1-Cyclohexene-1-acetic acid, 4-(acetyloxy)-, ethyl ester(113931-84-3)

Safety Data

• Hazardous Substances Data: 113931-84-3(Hazardous Substances Data)

Upstream product

• 101508-34-3 (4-Acetoxy-1-bromo-cyclohexyl)-acetic acid ethyl ester 
• 101489-33-2 (4-Acetoxy-1-hydroxy-cyclohexyl)-acetic acid ethyl ester 

Relevant articles and documents

STEREOSTRUCTURE OF RENGYOL AND ISORENGYOL, PHENYLETHANOIDS OF FORSYTHIA SUSPENSA

Determination of the stereostructure of rengyol (1), a novel nonaromatic phenylethanoid natural product isolated from Forsythia suspensa, by synthetic means has been described.The Reformatsky reaction of 4-acetoxycyclohexanone with ethyl bromoacetate afforded two isomeric acetoxy esters (5, 6) and the one (5) which has an equatorial acetoxyl group yielded on LAH reduction a triol identified as rengyol (1).The isomer (7), obtained similarly from the other isomeric acetoxy ester (6), has also been isolated from the natural source and is named isorengyol.Further, dehydratation of the esters (5, 6) and subsequent pyrolytic deacetoxylation afforded a 1,3-cyclohaxadiene derivative (12), which on photosensitized cis-dioxygenation, followed by reduction, yielded rengyol (1) establishing its stereostructure to have 1,4-cis-cyclohexanediol system.These results supported the previous conclusion based on the 1H and 13C NMR spectral data.