114004-30-7

Basic information

• Product Name: 1,6-Hexanediol, mono(4-nitrobenzoate)
• CAS NO: 114004-30-7
• Molecular Formula: C13H17NO5
• Molecular Weight: 267.282
• Mol File: 114004-30-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,6-Hexanediol, mono(4-nitrobenzoate)(CAS DataBase Reference)
• NIST Chemistry Reference: 1,6-Hexanediol, mono(4-nitrobenzoate)(114004-30-7)
• EPA Substance Registry System: 1,6-Hexanediol, mono(4-nitrobenzoate)(114004-30-7)

Safety Data

• Hazardous Substances Data: 114004-30-7(Hazardous Substances Data)

Upstream product

• 629-11-8 1,6-hexanediol 
• 62-23-7 4-nitro-benzoic acid 

Downstream Products

• 444321-71-5 4-(6-hydroxyhexyloxy)phenylenecarbonyloxy 6'-hexane 1'-ol 
• 869657-87-4 6-bromohexyl 4-nitrobenzoate 

Relevant articles and documents

Selective Monoesterification of Symmetrical Diols Using Resin-Bound Triphenylphosphine

Coupling reactions to make esters and amides are among the most widely used organic transformations. We report efficient procedures for amide bond formation and for the monoesterification of symmetrical diols in excellent yields without any requirement for high dilution or slow addition using resin-bound triarylphosphonium iodide. Easy purification, low moisture sensitivity, and good to excellent yields of the products are the major advantages of this protocol.

Mesogens and methods for their synthesis and use

New, efficient methods for making novel platform molecules and polymerizable mesogens are provided, as well as the novel mesogens and methods of using same.

Ytterbium triflate mediated selective deprotection of acetates

Ytterbium triflate mediated selective deprotection of acetates in isopropyl alcohol at reflux temperature is reported. Unlike hafnium triflate, under the present reaction conditions aryl acetates also undergo deacetylation instead of Fries migration.