114738-38-4

Basic information

• Product Name: 1-hydroperoxy-3-phenylcyclopent-3-ene
• Synonyms: 1-hydroperoxy-3-phenylcyclopent-3-ene
• CAS NO: 114738-38-4
• Molecular Weight: 176.215
• Mol File: 114738-38-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-hydroperoxy-3-phenylcyclopent-3-ene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-hydroperoxy-3-phenylcyclopent-3-ene(114738-38-4)
• EPA Substance Registry System: 1-hydroperoxy-3-phenylcyclopent-3-ene(114738-38-4)

Safety Data

• Hazardous Substances Data: 114738-38-4(Hazardous Substances Data)

Upstream product

• 113331-85-4 (1R^*,3R^*,4S^*)-4-phenylcyclopentane-1,3-diol 
• 591-51-5 phenyllithium 
• 114738-30-6 (3R^*,4S^*)-3-<(tert-butyldimethylsilyl)oxy>-4-phenylcyclopentan-1-one 
• 69404-97-3 2,4-pentane dione t butyl dimethyl silyl enol ether 
• 61305-35-9 4-[(tert-butyldimethylsilyl)oxy]cyclopent-2-enone 

Downstream Products

• 27856-20-8 1-hydroxy-3-phenylcyclopent-3-ene 

Relevant articles and documents

Formation of 1-Phenyl-2,3-dioxabicycloheptane in the Reaction of 1,3-Dibromo-4-phenylcyclopentane with Hydrogen Peroxide in the Presence of Silver Trifluoroacetate

Reaction of 1,3-dibromo-4-phenylcyclopentane (23), prepared from 4-hydroxycyclopent-2-en-1-one (10) in a stereocontrolled manner, or its stereoisomer 24 with anhydrous hydrogen peroxide in the presence of silver trifluoroacetate in ether gave 1-phenyl-2,3-dioxabicycloheptane (25) mainly as a rearranged product.The expected 5-phenyl-2,3-dioxabicycloheptane (8) and phenylcyclopentenyl hydroperoxides 26 and 27 were also formed in this reaction.An authentic sample of endoperoxide 8 was prepared by using peroxide transfer reaction between bis(tri-n-butyltin)peroxide and bistriflate of cis-diol 35.The stereochemistry of the endoperoxide 8 and related compounds in this series was confirmed by correlation with the data from X-ray crystallographic analysis of the diacetate of diol 21 obtained from endoperoxide 8 by stannous chloride reduction.